Water-Assisted growth of uniform 100 mm diameter SWCNT arrays

Roman M. Wyss, Jennifer E. Klare, Hyung Gyu Park, Aleksandr Noy, Olgica Bakajin, Valentin Lulevich

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

We report a simple method for growing high-quality single-walled carbon nanotube (SWCNT) arrays on 100 mm wafers via the addition of water vapor to highly purified gases during the CNT growth step. We show that adding a small amount of water during growth helps to create a uniform catalyst distribution and yields high-quality (Raman G/D of 26 ± 3), high-density (up to 6 × 1011 cm-2) and uniform SWCNT arrays on 100 mm large wafers. We rationalize our finding by suggesting that the addition of water decreases catalyst mobility, preventing its coarsening at higher temperatures. We also report a new mechanism of catalyst inactivation in wafer-scale growth using ultrapurified gas sources by the formation of large, 5 ± 3 μm iron particles. We found such formations to be common for substrates with large temperature gradients, such as for wafers processed in a typical cold-wall chemical vapor deposition reactor.

Original languageEnglish (US)
Pages (from-to)21019-21025
Number of pages7
JournalACS Applied Materials and Interfaces
Volume6
Issue number23
DOIs
StatePublished - Dec 10 2014
Externally publishedYes

Fingerprint

Single-walled carbon nanotubes (SWCN)
Catalysts
Water
Gases
Steam
Coarsening
Thermal gradients
Water vapor
Chemical vapor deposition
Iron
Substrates
Temperature

Keywords

  • aligned SWCNT array
  • catalyst inactivation
  • catalyst mobility
  • catalyst ripening
  • wafer scale CNT synthesis
  • water assisted SWCNT growth

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Wyss, R. M., Klare, J. E., Park, H. G., Noy, A., Bakajin, O., & Lulevich, V. (2014). Water-Assisted growth of uniform 100 mm diameter SWCNT arrays. ACS Applied Materials and Interfaces, 6(23), 21019-21025. https://doi.org/10.1021/am505692a

Water-Assisted growth of uniform 100 mm diameter SWCNT arrays. / Wyss, Roman M.; Klare, Jennifer E.; Park, Hyung Gyu; Noy, Aleksandr; Bakajin, Olgica; Lulevich, Valentin.

In: ACS Applied Materials and Interfaces, Vol. 6, No. 23, 10.12.2014, p. 21019-21025.

Research output: Contribution to journalArticle

Wyss, RM, Klare, JE, Park, HG, Noy, A, Bakajin, O & Lulevich, V 2014, 'Water-Assisted growth of uniform 100 mm diameter SWCNT arrays', ACS Applied Materials and Interfaces, vol. 6, no. 23, pp. 21019-21025. https://doi.org/10.1021/am505692a
Wyss, Roman M. ; Klare, Jennifer E. ; Park, Hyung Gyu ; Noy, Aleksandr ; Bakajin, Olgica ; Lulevich, Valentin. / Water-Assisted growth of uniform 100 mm diameter SWCNT arrays. In: ACS Applied Materials and Interfaces. 2014 ; Vol. 6, No. 23. pp. 21019-21025.
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