Two-step synthesis of the immunogenic bacterial glycolipid BbGL1

Suvarn S. Kulkarni; Jacquelyn Gervay-Hague

doi:10.1021/ol801780c

Two-step synthesis of the immunogenic bacterial glycolipid BbGL1

Suvarn S. Kulkarni, Jacquelyn Gervay-Hague

Chemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

(Chemical Equation Presented) Chemical synthesis of a bacterial glycolipid BbL1 is reported in two steps starting from per-0-TMS D-galactose. The key features are glycosyl iodide mediated β-stereoselective glycosylation in the absence of neighboring group participation and regioseiective acylation.

Original language	English (US)
Pages (from-to)	4739-4742
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	21
DOIs	https://doi.org/10.1021/ol801780c
State	Published - Dec 1 2008

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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abstract = "(Chemical Equation Presented) Chemical synthesis of a bacterial glycolipid BbL1 is reported in two steps starting from per-0-TMS D-galactose. The key features are glycosyl iodide mediated β-stereoselective glycosylation in the absence of neighboring group participation and regioseiective acylation.",

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