Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins

V. I. Bykov; T. A. Butenko; E. Sh Finkel'shtein; Paul Henderson

doi:10.1016/0304-5102(93)E0310-D

Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins

V. I. Bykov, T. A. Butenko, E. Sh Finkel'shtein, Paul Henderson

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.

Original language	English (US)
Pages (from-to)	111-116
Number of pages	6
Journal	Journal of Molecular Catalysis
Volume	90
Issue number	1-2
DOIs	https://doi.org/10.1016/0304-5102(93)E0310-D
State	Published - 1994
Externally published	Yes

Keywords

metathesis
monoene
olefins
pheromone components

ASJC Scopus subject areas

Engineering(all)

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10.1016/0304-5102(93)E0310-D

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title = "Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins",

abstract = "Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.",

keywords = "metathesis, monoene, olefins, pheromone components",

author = "Bykov, {V. I.} and Butenko, {T. A.} and Finkel'shtein, {E. Sh} and Paul Henderson",

year = "1994",

doi = "10.1016/0304-5102(93)E0310-D",

language = "English (US)",

volume = "90",

pages = "111--116",

journal = "Journal of Molecular Catalysis",

issn = "0304-5102",

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number = "1-2",

}

TY - JOUR

T1 - Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins

AU - Bykov, V. I.

AU - Butenko, T. A.

AU - Finkel'shtein, E. Sh

AU - Henderson, Paul

PY - 1994

Y1 - 1994

N2 - Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.

AB - Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.

KW - metathesis

KW - monoene

KW - olefins

KW - pheromone components

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U2 - 10.1016/0304-5102(93)E0310-D

DO - 10.1016/0304-5102(93)E0310-D

M3 - Article

AN - SCOPUS:0028427458

VL - 90

SP - 111

EP - 116

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

SN - 0304-5102

IS - 1-2

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