Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins

V. I. Bykov; T. A. Butenko; E. Sh Finkel'shtein; Paul Henderson

doi:10.1016/0304-5102(93)E0310-D

Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins

V. I. Bykov, T. A. Butenko, E. Sh Finkel'shtein, Paul Henderson

Research output: Contribution to journal › Article

15 Scopus citations

Abstract

Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.

Original language	English (US)
Pages (from-to)	111-116
Number of pages	6
Journal	Journal of Molecular Catalysis
Volume	90
Issue number	1-2
DOIs	https://doi.org/10.1016/0304-5102(93)E0310-D
Publication status	Published - 1994
Externally published	Yes

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Keywords

metathesis
monoene
olefins
pheromone components

ASJC Scopus subject areas

Engineering(all)

Cite this

Bykov, V. I., Butenko, T. A., Finkel'shtein, E. S., & Henderson, P. (1994). Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins. Journal of Molecular Catalysis, 90(1-2), 111-116. https://doi.org/10.1016/0304-5102(93)E0310-D

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abstract = "Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.",

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AU - Henderson, Paul

PY - 1994

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KW - pheromone components

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10.1016/0304-5102(93)E0310-D