Abstract
Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 111-116 |
| Number of pages | 6 |
| Journal | Journal of Molecular Catalysis |
| Volume | 90 |
| Issue number | 1-2 |
| DOIs | |
| State | Published - 1994 |
| Externally published | Yes |
Keywords
- metathesis
- monoene
- olefins
- pheromone components
ASJC Scopus subject areas
- Engineering(all)
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Bykov, V. I., Butenko, T. A., Finkel'shtein, E. S., & Henderson, P. (1994). Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins. Journal of Molecular Catalysis, 90(1-2), 111-116. https://doi.org/10.1016/0304-5102(93)E0310-D