Abstract
Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 111-116 |
| Number of pages | 6 |
| Journal | Journal of Molecular Catalysis |
| Volume | 90 |
| Issue number | 1-2 |
| DOIs | |
| State | Published - 1994 |
| Externally published | Yes |
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Keywords
- metathesis
- monoene
- olefins
- pheromone components
ASJC Scopus subject areas
- Engineering(all)
Cite this
Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins. / Bykov, V. I.; Butenko, T. A.; Finkel'shtein, E. Sh; Henderson, Paul.
In: Journal of Molecular Catalysis, Vol. 90, No. 1-2, 1994, p. 111-116.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins
AU - Bykov, V. I.
AU - Butenko, T. A.
AU - Finkel'shtein, E. Sh
AU - Henderson, Paul
PY - 1994
Y1 - 1994
N2 - Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.
AB - Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.
KW - metathesis
KW - monoene
KW - olefins
KW - pheromone components
UR - http://www.scopus.com/inward/record.url?scp=0028427458&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0028427458&partnerID=8YFLogxK
U2 - 10.1016/0304-5102(93)E0310-D
DO - 10.1016/0304-5102(93)E0310-D
M3 - Article
AN - SCOPUS:0028427458
VL - 90
SP - 111
EP - 116
JO - Journal of Molecular Catalysis
JF - Journal of Molecular Catalysis
SN - 0304-5102
IS - 1-2
ER -