Synthesis of monoene pheromone components having a double bond in positions 6-11 using cometathesis of cycloolefins with α-olefins

V. I. Bykov, T. A. Butenko, E. Sh Finkel'shtein, Paul Henderson

Research output: Contribution to journalArticle

15 Scopus citations

Abstract

Cometathesis of cycloolefins, 1, with linearα-alkenes, 2, using molybdenum pentachloride catalyst with a cocatalyst of tetramethyltin followed by hydroboration of the resulting α,ω-dienes 3 with 9-borabicyclo [3.3.1] nonane (9-BBN) and oxidation or carbonylation of the resulting boranes, 4, is a convenient route to Δ6-11 monoolefin derivatives.

Original languageEnglish (US)
Pages (from-to)111-116
Number of pages6
JournalJournal of Molecular Catalysis
Volume90
Issue number1-2
DOIs
Publication statusPublished - 1994
Externally publishedYes

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Keywords

  • metathesis
  • monoene
  • olefins
  • pheromone components

ASJC Scopus subject areas

  • Engineering(all)

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