Surface tensions of inorganic multicomponent aqueous electrolyte solutions and melts

Cari S. Dutcher, Anthony S. Wexler, Simon L. Clegg

Research output: Contribution to journalArticle

66 Citations (Scopus)

Abstract

A semiempirical model is presented that predicts surface tensions (σ) of aqueous electrolyte solutions and their mixtures, for concentrations ranging from infinitely dilute solution to molten salt. The model requires, at most, only two temperature-dependent terms to represent surface tensions of either pure aqueous solutions, or aqueous or molten mixtures, over the entire composition range. A relationship was found for the coefficients of the equation σ = c1 + c2T (where T (K) is temperature) for molten salts in terms of ion valency and radius, melting temperature, and salt molar volume. Hypothetical liquid surface tensions can thus be estimated for electrolytes for which there are no data, or which do not exist in molten form. Surface tensions of molten (single) salts, when extrapolated to normal temperatures, were found to be consistent with data for aqueous solutions. This allowed surface tensions of very concentrated, supersaturated, aqueous solutions to be estimated. The model has been applied to the following single electrolytes over the entire concentration range, using data for aqueous solutions over the temperature range 233-523 K, and extrapolated surface tensions of molten salts and pure liquid electrolytes: HCl, HNO3, H2SO4, NaCl, NaNO3, Na2SO 4, NaHSO4, Na2CO3, NaHCO 3, NaOH, NH4Cl, NH4NO3, (NH 4)2SO4, NH4HCO3, NH 4OH, KCl, KNO3, K2SO4, K 2CO3, KHCO3, KOH, CaCl2, Ca(NO 3)2, MgCl2, Mg(NO3)2, and MgSO4. The average absolute percentage error between calculated and experimental surface tensions is 0.80% (for 2389 data points). The model extrapolates smoothly to temperatures as low as 150 K. Also, the model successfully predicts surface tensions of ternary aqueous mixtures; the effect of salt-salt interactions in these calculations was explored.

Original languageEnglish (US)
Pages (from-to)12216-12230
Number of pages15
JournalJournal of Physical Chemistry A
Volume114
Issue number46
DOIs
StatePublished - Nov 25 2010

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Electrolytes
Surface tension
interfacial tension
electrolytes
Salts
Molten materials
molten salts
aqueous solutions
salts
temperature
Temperature
Magnesium Chloride
liquid surfaces
Liquids
Density (specific gravity)
Melting point
melting
Ions
radii
coefficients

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Surface tensions of inorganic multicomponent aqueous electrolyte solutions and melts. / Dutcher, Cari S.; Wexler, Anthony S.; Clegg, Simon L.

In: Journal of Physical Chemistry A, Vol. 114, No. 46, 25.11.2010, p. 12216-12230.

Research output: Contribution to journalArticle

Dutcher, Cari S. ; Wexler, Anthony S. ; Clegg, Simon L. / Surface tensions of inorganic multicomponent aqueous electrolyte solutions and melts. In: Journal of Physical Chemistry A. 2010 ; Vol. 114, No. 46. pp. 12216-12230.
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abstract = "A semiempirical model is presented that predicts surface tensions (σ) of aqueous electrolyte solutions and their mixtures, for concentrations ranging from infinitely dilute solution to molten salt. The model requires, at most, only two temperature-dependent terms to represent surface tensions of either pure aqueous solutions, or aqueous or molten mixtures, over the entire composition range. A relationship was found for the coefficients of the equation σ = c1 + c2T (where T (K) is temperature) for molten salts in terms of ion valency and radius, melting temperature, and salt molar volume. Hypothetical liquid surface tensions can thus be estimated for electrolytes for which there are no data, or which do not exist in molten form. Surface tensions of molten (single) salts, when extrapolated to normal temperatures, were found to be consistent with data for aqueous solutions. This allowed surface tensions of very concentrated, supersaturated, aqueous solutions to be estimated. The model has been applied to the following single electrolytes over the entire concentration range, using data for aqueous solutions over the temperature range 233-523 K, and extrapolated surface tensions of molten salts and pure liquid electrolytes: HCl, HNO3, H2SO4, NaCl, NaNO3, Na2SO 4, NaHSO4, Na2CO3, NaHCO 3, NaOH, NH4Cl, NH4NO3, (NH 4)2SO4, NH4HCO3, NH 4OH, KCl, KNO3, K2SO4, K 2CO3, KHCO3, KOH, CaCl2, Ca(NO 3)2, MgCl2, Mg(NO3)2, and MgSO4. The average absolute percentage error between calculated and experimental surface tensions is 0.80{\%} (for 2389 data points). The model extrapolates smoothly to temperatures as low as 150 K. Also, the model successfully predicts surface tensions of ternary aqueous mixtures; the effect of salt-salt interactions in these calculations was explored.",
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