Structure and polymorphism of the 10.10.10 Simmons and Park cryptand

A. S. Batsanov; A. J. Blake; N. M. Hext; M. Mascal

Structure and polymorphism of the 10.10.10 Simmons and Park cryptand

A. S. Batsanov, A. J. Blake, N. M. Hext, M. Mascal

Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The first crystal structure of a 10.10.10 cryptand has been determined, during which an unusual single crystal phase transition was observed; at room temperature, crystals of macrobicycle 1d are monoclinic (α) but undergo a first-order topotactic phase change at 207 K to a triclinic (β) lattice; full structure determinations at 150 and 210 K were carried out and show that both phases adopt the in-in cryptand conformation.

Original language	English (US)
Pages (from-to)	127-128
Number of pages	2
Journal	Chemical Communications
Issue number	1
State	Published - Jan 7 2001

ASJC Scopus subject areas

Chemistry(all)

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title = "Structure and polymorphism of the 10.10.10 Simmons and Park cryptand",

abstract = "The first crystal structure of a 10.10.10 cryptand has been determined, during which an unusual single crystal phase transition was observed; at room temperature, crystals of macrobicycle 1d are monoclinic (α) but undergo a first-order topotactic phase change at 207 K to a triclinic (β) lattice; full structure determinations at 150 and 210 K were carried out and show that both phases adopt the in-in cryptand conformation.",

author = "Batsanov, {A. S.} and Blake, {A. J.} and Hext, {N. M.} and M. Mascal",

year = "2001",

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journal = "Chemical Communications",

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AU - Blake, A. J.

AU - Hext, N. M.

AU - Mascal, M.

PY - 2001/1/7

Y1 - 2001/1/7

N2 - The first crystal structure of a 10.10.10 cryptand has been determined, during which an unusual single crystal phase transition was observed; at room temperature, crystals of macrobicycle 1d are monoclinic (α) but undergo a first-order topotactic phase change at 207 K to a triclinic (β) lattice; full structure determinations at 150 and 210 K were carried out and show that both phases adopt the in-in cryptand conformation.

AB - The first crystal structure of a 10.10.10 cryptand has been determined, during which an unusual single crystal phase transition was observed; at room temperature, crystals of macrobicycle 1d are monoclinic (α) but undergo a first-order topotactic phase change at 207 K to a triclinic (β) lattice; full structure determinations at 150 and 210 K were carried out and show that both phases adopt the in-in cryptand conformation.

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