Sterols in marine invertebrates. 49. Isolation and structure elucidation of eight new polyhydroxylated sterols from the soft coral Sinularia dissecta

Barbara M. Jagodzinska, James Trimmer, William Fenical, Carl Djerassi

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

A new group of polyhydroxylated sterols - all of them possessing an 11α-hydroxy substituent of potential utility as corticosteroid intermediates - has been isolated from the soft coral Sinularia dissecta. Their general structure was deduced from spectral data (500-MHz and 360-MHz 1H and 13C NMR and MS) and their stereochemistry was determined by correlating the respective spectral data (1H and 13C NMR) with those of synthetic sterols with similar structure and known configuration.

Original languageEnglish (US)
Pages (from-to)1435-1439
Number of pages5
JournalJournal of Organic Chemistry
Volume50
Issue number9
StatePublished - 1985
Externally publishedYes

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Sterols
Nuclear magnetic resonance
Stereochemistry
Adrenal Cortex Hormones
Invertebrates

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Sterols in marine invertebrates. 49. Isolation and structure elucidation of eight new polyhydroxylated sterols from the soft coral Sinularia dissecta. / Jagodzinska, Barbara M.; Trimmer, James; Fenical, William; Djerassi, Carl.

In: Journal of Organic Chemistry, Vol. 50, No. 9, 1985, p. 1435-1439.

Research output: Contribution to journalArticle

Jagodzinska, Barbara M. ; Trimmer, James ; Fenical, William ; Djerassi, Carl. / Sterols in marine invertebrates. 49. Isolation and structure elucidation of eight new polyhydroxylated sterols from the soft coral Sinularia dissecta. In: Journal of Organic Chemistry. 1985 ; Vol. 50, No. 9. pp. 1435-1439.
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