Solution preparation of Ge nanoparticles with chemically tailored surfaces

Boyd R. Taylor; Glenn A. Fox; Lousia J. Hope-Weeks; Robert S. Maxwell; Susan M. Kauzlarich; Howard W H Lee

doi:10.1016/S0921-5107(02)00297-0

Solution preparation of Ge nanoparticles with chemically tailored surfaces

Boyd R. Taylor, Glenn A. Fox, Lousia J. Hope-Weeks, Robert S. Maxwell, Susan M. Kauzlarich, Howard W H Lee

Chemistry

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The solution preparation of Ge nanoparticles with chemically tailored surfaces was discussed. The metathesis of the Zintl salts NaGe, KGe and Mg₂Ge with GeCl₄ in boiling glymes was used to prepare Ge nanoparticles. Results showed that the reaction between Mg₂Ge and GeCl₄ in refluxing diglyme produces Ge nanoparticles in high yields and surface of these particles may be terminated using Grignard reagents.

Original language	English (US)
Pages (from-to)	90-93
Number of pages	4
Journal	Materials Science and Engineering B: Solid-State Materials for Advanced Technology
Volume	96
Issue number	2
DOIs	https://doi.org/10.1016/S0921-5107(02)00297-0
State	Published - Nov 1 2002

Keywords

Alkyllithium reagents
Ge nanoparticles
Zintl salts

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Materials Science(all)
Condensed Matter Physics

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Solution preparation of Ge nanoparticles with chemically tailored surfaces. / Taylor, Boyd R.; Fox, Glenn A.; Hope-Weeks, Lousia J.; Maxwell, Robert S.; Kauzlarich, Susan M.; Lee, Howard W H.

In: Materials Science and Engineering B: Solid-State Materials for Advanced Technology, Vol. 96, No. 2, 01.11.2002, p. 90-93.

Research output: Contribution to journal › Article › peer-review

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abstract = "The solution preparation of Ge nanoparticles with chemically tailored surfaces was discussed. The metathesis of the Zintl salts NaGe, KGe and Mg2Ge with GeCl4 in boiling glymes was used to prepare Ge nanoparticles. Results showed that the reaction between Mg2Ge and GeCl4 in refluxing diglyme produces Ge nanoparticles in high yields and surface of these particles may be terminated using Grignard reagents.",

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AU - Lee, Howard W H

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