Abstract
(Equation Presented) Oligosaccharides composed of 1,6-glucosyl residues have been prepared from glucosyl iodides. The reactions are highly stereoselective, giving the α-glycosides as the only isolated products in yields ranging from 84% to 94%. Oligomer synthesis can take place in an iterative 1 + 1 + 1 fashion or in a convergent manner where dimer iodides serve as donors for higher order acceptors.
Original language | English (US) |
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Pages (from-to) | 2039-2042 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 4 |
Issue number | 12 |
DOIs | |
State | Published - Jun 13 2002 |
ASJC Scopus subject areas
- Molecular Medicine