Abstract
(Equation Presented) Oligosaccharides composed of 1,6-glucosyl residues have been prepared from glucosyl iodides. The reactions are highly stereoselective, giving the α-glycosides as the only isolated products in yields ranging from 84% to 94%. Oligomer synthesis can take place in an iterative 1 + 1 + 1 fashion or in a convergent manner where dimer iodides serve as donors for higher order acceptors.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2039-2042 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 4 |
| Issue number | 12 |
| DOIs | |
| State | Published - Jun 13 2002 |
ASJC Scopus subject areas
- Molecular Medicine
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Cite this
Lam, S. N., & Gervay-Hague, J. (2002). Solution-Phase Hexasaccharide Synthesis Using Glucosyl Iodides. Organic Letters, 4(12), 2039-2042. https://doi.org/10.1021/ol025887d