Solution-Phase Hexasaccharide Synthesis Using Glucosyl Iodides

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Abstract

(Equation Presented) Oligosaccharides composed of 1,6-glucosyl residues have been prepared from glucosyl iodides. The reactions are highly stereoselective, giving the α-glycosides as the only isolated products in yields ranging from 84% to 94%. Oligomer synthesis can take place in an iterative 1 + 1 + 1 fashion or in a convergent manner where dimer iodides serve as donors for higher order acceptors.

Original languageEnglish (US)
Pages (from-to)2039-2042
Number of pages4
JournalOrganic Letters
Volume4
Issue number12
DOIs
StatePublished - Jun 13 2002

ASJC Scopus subject areas

  • Molecular Medicine

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