Secondary organics and atmospheric cloud condensation nuclei production

Veli Matti Kerminen, Aki Virkkula, Risto Hillamo, Anthony S. Wexler, Markku Kulmala

Research output: Contribution to journalArticle

77 Scopus citations

Abstract

The influence of secondary organics on atmospheric cloud condensation nuclei (CCN) production was investigated using a zero-dimensional box model that simulates the production of secondary organics in the gas phase, the transportation of these organics from gas to the particulate phase, and the resulting growth of the particles. Model simulations demonstrated that the growth of nanometer-size nuclei to a CCN size requires the presence of organics of extremely low volatility. These "nonvolatile" organics need to have saturation vapors pressures of the order of 0.01-0.1 parts per trillion or lower and, in order to induce sufficient nuclei growth, must have gas phase production rates of the order of 0.3-1 μg m-3 d-1 under conditions typical for continental background areas. As the nuclei grow in size, they start to uptake volatile organics more efficiently. As a result, organic matter in both the nuclei grown into a CCN size and in the preexisting accumulation mode particles is expected to be dominated by "low-volatile" organics rather than organics that actually are responsible for the nuclei growth. The modeling results suggest that the monoterpene oxidation products identified so far in field or laboratory experiments, although important contributors to secondary particulate matter, are unlikely to be the ones that grow nuclei to a CCN size. In field experiments, positive identification of organics producing new CCN would require information on the chemical composition of particles smaller than about 0.1 μm in diameter, which is the size range where nonvolatile organics are likely to be enriched compared with other secondary or primary organics. Since the gas phase production rate of nonvolatile organics needs not to be very large in order to induce significant nuclei growth, more attention should also be paid to reaction products that have minor yields in smog chamber experiments.

Original languageEnglish (US)
Article number1999JD901203
Pages (from-to)9255-9264
Number of pages10
JournalJournal of Geophysical Research: Atmospheres
Volume105
Issue numberD7
StatePublished - Apr 16 2000
Externally publishedYes

ASJC Scopus subject areas

  • Geochemistry and Petrology
  • Geophysics
  • Earth and Planetary Sciences (miscellaneous)
  • Space and Planetary Science
  • Atmospheric Science
  • Astronomy and Astrophysics
  • Oceanography

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  • Cite this

    Kerminen, V. M., Virkkula, A., Hillamo, R., Wexler, A. S., & Kulmala, M. (2000). Secondary organics and atmospheric cloud condensation nuclei production. Journal of Geophysical Research: Atmospheres, 105(D7), 9255-9264. [1999JD901203].