Reductive dehydroxy coupling of 2-(hydroxymethyl)indenes to prepare ethano-bridged bis(2-indenyl) ansa-titanocenes

Hasan Palandoken, Justin K. Wyatt, Shawn R. Hitchcock, Marilyn M. Olmstead, Michael H. Nantz

Research output: Contribution to journal › Article

13 Citations (Scopus)

Abstract

New examples of ansa-titanocenes derived from 1,2-bis(2-indenyl)ethane have been prepared. The titanium-mediated reductive coupling of 2-(hydroxymethyl)indenes provided a convenient method for substrate dimerization. Alkyl substitution of the indene ring at C(3) improved the regioselectivity of the reductive coupling to provide the ethylene bis(2-indenyl)ansa-ligands in 29-62% yield.

Original languageEnglish (US)
Pages (from-to)338-347
Number of pages10
JournalJournal of Organometallic Chemistry
Volume579
Issue number1-2
StatePublished - May 5 1999

Fingerprint

Indenes
indene
Regioselectivity
Ethane
Dimerization
Titanium
Ethylene
Substitution reactions
Ligands
Substrates
dimerization
ethane
ethylene
titanium
substitutes
ligands
rings

Keywords

  • ansa-Titanocenes
  • Chiral
  • Indenyl
  • Metallocene
  • Reductive coupling
  • Titanium

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Palandoken, H., Wyatt, J. K., Hitchcock, S. R., Olmstead, M. M., & Nantz, M. H. (1999). Reductive dehydroxy coupling of 2-(hydroxymethyl)indenes to prepare ethano-bridged bis(2-indenyl) ansa-titanocenes. Journal of Organometallic Chemistry, 579(1-2), 338-347.

Reductive dehydroxy coupling of 2-(hydroxymethyl)indenes to prepare ethano-bridged bis(2-indenyl) ansa-titanocenes. / Palandoken, Hasan; Wyatt, Justin K.; Hitchcock, Shawn R.; Olmstead, Marilyn M.; Nantz, Michael H.

In: Journal of Organometallic Chemistry, Vol. 579, No. 1-2, 05.05.1999, p. 338-347.

Research output: Contribution to journal › Article

Palandoken, H, Wyatt, JK, Hitchcock, SR, Olmstead, MM & Nantz, MH 1999, 'Reductive dehydroxy coupling of 2-(hydroxymethyl)indenes to prepare ethano-bridged bis(2-indenyl) ansa-titanocenes', Journal of Organometallic Chemistry, vol. 579, no. 1-2, pp. 338-347.
Palandoken H, Wyatt JK, Hitchcock SR, Olmstead MM, Nantz MH. Reductive dehydroxy coupling of 2-(hydroxymethyl)indenes to prepare ethano-bridged bis(2-indenyl) ansa-titanocenes. Journal of Organometallic Chemistry. 1999 May 5;579(1-2):338-347.
Palandoken, Hasan ; Wyatt, Justin K. ; Hitchcock, Shawn R. ; Olmstead, Marilyn M. ; Nantz, Michael H. / Reductive dehydroxy coupling of 2-(hydroxymethyl)indenes to prepare ethano-bridged bis(2-indenyl) ansa-titanocenes. In: Journal of Organometallic Chemistry. 1999 ; Vol. 579, No. 1-2. pp. 338-347.
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