Protonic conduction in imidazole: A solid-state 15N NMR study

Benjamin S. Hickman, Mark Mascal, Jeremy J. Titman, Ian G. Wood

Research output: Contribution to journalArticle

73 Scopus citations

Abstract

Reports of protonic conductivity in crystalline imidazole describe a pronounced anisotropy in the transport of H+ with respect to crystallographic direction. Since charge is carried mainly along imidazole's hydrogen bonding axis (C), it has long been hypothesized that the phenomenon involves the tunneling of protons through hydrogen bonds. A two-dimensional nitrogen-15 exchange NMR study of 15N-labeled imidazole, however, demonstrates that the conduction mechanism does not involve the reorientation of the imidazole ring invoked in current models.

Original languageEnglish (US)
Pages (from-to)11486-11490
Number of pages5
JournalJournal of the American Chemical Society
Volume121
Issue number49
DOIs
StatePublished - Dec 15 1999
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint Dive into the research topics of 'Protonic conduction in imidazole: A solid-state <sup>15</sup>N NMR study'. Together they form a unique fingerprint.

  • Cite this

    Hickman, B. S., Mascal, M., Titman, J. J., & Wood, I. G. (1999). Protonic conduction in imidazole: A solid-state 15N NMR study. Journal of the American Chemical Society, 121(49), 11486-11490. https://doi.org/10.1021/ja991401l