Probing electronics as a function of size and surface of colloidal germanium nanocrystals

Alexandra L. Holmes, Jeanette Hütges, Anna Reckmann, Elayaraja Muthuswamy, Klaus Meerholz, Susan M. Kauzlarich

Research output: Contribution to journalArticle

15 Scopus citations

Abstract

Inorganic semiconductor nanoparticles are of significant interest for applications that benefit from their size-dependent properties. The work presented here focuses on the characterization of solution-based microwave synthesized Ge nanocrystals (NCs). Three differently capped Ge NCs were investigated: oleylamine (OAM), dodecanethiol (DDT), and a functionalized N4,N4,N4′,N4′-tetraphenylbiphenyl-4,4′-diamine (TPD) ligand, which is commonly used as hole-transporting units. The optical gaps followed the expected trend for quantum confinement; however, the absolute value depended upon the ligand. We found that the DDT-capped Ge NCs feature consistently larger bandgaps than OAM-capped Ge NCs of a similar size. Cyclic voltammetry (CV) was used to determine the valence band energy for OAM-capped Ge NCs, and the conduction band energy was estimated from the optical gap. By contrast, DDT-capped Ge NCs and the OAM/DDT-capped Ge NCs did not exhibit an oxidative signal in the cyclic voltammetry. This was attributed to the removal of surface defects of OAM-capped Ge NCs through stronger Ge-S surface bonds. TPD-capped Ge NCs were investigated and showed a shift to slightly higher oxidation potential compared with the free ligand and bandgap values in between that of the OAM-capped and DDT-capped Ge NCs. The higher oxidation potential is attributed to TPD orientation, and the bandgap value reflects the lower number of Ge-S bonds on the surface due to ligand sterics.

Original languageEnglish (US)
Pages (from-to)5671-5678
Number of pages8
JournalJournal of Physical Chemistry C
Volume119
Issue number10
DOIs
StatePublished - Mar 12 2015

    Fingerprint

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Holmes, A. L., Hütges, J., Reckmann, A., Muthuswamy, E., Meerholz, K., & Kauzlarich, S. M. (2015). Probing electronics as a function of size and surface of colloidal germanium nanocrystals. Journal of Physical Chemistry C, 119(10), 5671-5678. https://doi.org/10.1021/jp511929v