TY - JOUR
T1 - Precedent and theory unite in the hypothesis of a highly selective fluoride receptor
AU - Mascal, Mark
PY - 2006/4/28
Y1 - 2006/4/28
N2 - Room for a small one: A series of [1,3,5]cyclophane-based receptors incorporating triazine, cyanuric acid, or boroxine rings are predicted to strongly complex fluoride ions by a combination of anion-π interactions and ion-pair reinforced hydrogen bonding, while size-excluding the larger chloride anion. The top view of a calculated structure of the triazine cage with an included fluoride ion is shown. (Figure Presented).
AB - Room for a small one: A series of [1,3,5]cyclophane-based receptors incorporating triazine, cyanuric acid, or boroxine rings are predicted to strongly complex fluoride ions by a combination of anion-π interactions and ion-pair reinforced hydrogen bonding, while size-excluding the larger chloride anion. The top view of a calculated structure of the triazine cage with an included fluoride ion is shown. (Figure Presented).
KW - Ab initio calculations
KW - Anions
KW - Cyclophanes
KW - Host-guest systems
KW - Hydrogen bonding
UR - http://www.scopus.com/inward/record.url?scp=33746191905&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33746191905&partnerID=8YFLogxK
U2 - 10.1002/anie.200504417
DO - 10.1002/anie.200504417
M3 - Article
C2 - 16550622
AN - SCOPUS:33746191905
VL - 45
SP - 2890
EP - 2893
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 18
ER -