Abstract
Collision-induced dissociations of organometallic complexes Cu(RCN)+, generated by the reaction of Cu+ with linear nitriles in the gas phase, generates products distinct from that of M(RCN)+ complexes (M = Fe, Co, Ni), While the gas-phase chemistry of the latter is well-described in terms of an end-on coordination of the type RCN-M+, the dissociation products of the RCN/Cu+ complexes point to a side-on complexation.
Original language | English (US) |
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Pages (from-to) | 2450-2451 |
Number of pages | 2 |
Journal | Organometallics |
Volume | 6 |
Issue number | 11 |
State | Published - 1987 |
Externally published | Yes |
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry