Abstract
Collision-induced dissociations of organometallic complexes Cu(RCN)+, generated by the reaction of Cu+ with linear nitriles in the gas phase, generates products distinct from that of M(RCN)+ complexes (M = Fe, Co, Ni), While the gas-phase chemistry of the latter is well-described in terms of an end-on coordination of the type RCN-M+, the dissociation products of the RCN/Cu+ complexes point to a side-on complexation.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2450-2451 |
| Number of pages | 2 |
| Journal | Organometallics |
| Volume | 6 |
| Issue number | 11 |
| State | Published - 1987 |
| Externally published | Yes |
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
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Lebrilla, C. B., Drewello, T., & Schwarz, H. (1987). Only the Cu+ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles. Organometallics, 6(11), 2450-2451.