Only the Cu+ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles

Carlito B Lebrilla; Thomas Drewello; Helmut Schwarz

Only the Cu⁺ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles

Carlito B Lebrilla, Thomas Drewello, Helmut Schwarz

Research output: Contribution to journal › Article

Abstract

Collision-induced dissociations of organometallic complexes Cu(RCN)⁺, generated by the reaction of Cu⁺ with linear nitriles in the gas phase, generates products distinct from that of M(RCN)⁺ complexes (M = Fe, Co, Ni), While the gas-phase chemistry of the latter is well-described in terms of an end-on coordination of the type RCN-M⁺, the dissociation products of the RCN/Cu⁺ complexes point to a side-on complexation.

Original language	English (US)
Pages (from-to)	2450-2451
Number of pages	2
Journal	Organometallics
Volume	6
Issue number	11
State	Published - 1987
Externally published	Yes

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Nitriles

nitriles

Gases

dissociation

vapor phases

collisions

Organometallics

products

Complexation

chemistry

ASJC Scopus subject areas

Inorganic Chemistry
Organic Chemistry

Cite this

Lebrilla, C. B., Drewello, T., & Schwarz, H. (1987). Only the Cu⁺ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles. Organometallics, 6(11), 2450-2451.

Only the Cu⁺ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles. / Lebrilla, Carlito B; Drewello, Thomas; Schwarz, Helmut.

In: Organometallics, Vol. 6, No. 11, 1987, p. 2450-2451.

Research output: Contribution to journal › Article

Lebrilla, CB, Drewello, T & Schwarz, H 1987, 'Only the Cu⁺ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles', Organometallics, vol. 6, no. 11, pp. 2450-2451.

Lebrilla CB, Drewello T, Schwarz H. Only the Cu⁺ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles. Organometallics. 1987;6(11):2450-2451.

Lebrilla, Carlito B ; Drewello, Thomas ; Schwarz, Helmut. / Only the Cu⁺ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles. In: Organometallics. 1987 ; Vol. 6, No. 11. pp. 2450-2451.

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abstract = "Collision-induced dissociations of organometallic complexes Cu(RCN)+, generated by the reaction of Cu+ with linear nitriles in the gas phase, generates products distinct from that of M(RCN)+ complexes (M = Fe, Co, Ni), While the gas-phase chemistry of the latter is well-described in terms of an end-on coordination of the type RCN-M+, the dissociation products of the RCN/Cu+ complexes point to a side-on complexation.",

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