Only the Cu+ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles

Carlito B Lebrilla, Thomas Drewello, Helmut Schwarz

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Collision-induced dissociations of organometallic complexes Cu(RCN)+, generated by the reaction of Cu+ with linear nitriles in the gas phase, generates products distinct from that of M(RCN)+ complexes (M = Fe, Co, Ni), While the gas-phase chemistry of the latter is well-described in terms of an end-on coordination of the type RCN-M+, the dissociation products of the RCN/Cu+ complexes point to a side-on complexation.

Original languageEnglish (US)
Pages (from-to)2450-2451
Number of pages2
JournalOrganometallics
Volume6
Issue number11
StatePublished - 1987
Externally publishedYes

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Nitriles
nitriles
Gases
dissociation
vapor phases
collisions
Organometallics
products
Complexation
chemistry

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Only the Cu+ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles. / Lebrilla, Carlito B; Drewello, Thomas; Schwarz, Helmut.

In: Organometallics, Vol. 6, No. 11, 1987, p. 2450-2451.

Research output: Contribution to journalArticle

Lebrilla, Carlito B ; Drewello, Thomas ; Schwarz, Helmut. / Only the Cu+ coordinated to the π-system of the C≡N group activates upon collision C-H and C-C bonds of nitriles. In: Organometallics. 1987 ; Vol. 6, No. 11. pp. 2450-2451.
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