New bio-based monomers: Tuneable polyester properties using branched diols from biomass

Sacha Pérocheau Arnaud, Linglin Wu, Maria Angelica Wong Chang, James W. Comerford, Thomas J. Farmer, Maximilian Schmid, Fei Chang, Zheng Li, Mark Mascal

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A family of monomers, including 2,5-hexandiol, 2,7-octandiol, 2,5-furandicarboxylic acid (FDCA), terephthalic acid (TA), and branched-chain adipic and pimelic acid derivatives, all find a common derivation in the biomass-derived platform molecule 5-(chloromethyl)furfural (CMF). The diol monomers, previously little known to polymer chemistry, have been combined with FDCA and TA derivatives to produce a range of novel polyesters. It is shown that the use of secondary diols leads to polymers with higher glass transition temperatures (Tg) than those prepared from their primary diol equivalents. Two methods of polymerisation were investigated, the first employing activation of the aromatic diacids via the corresponding diacid chlorides and the second using a transesterification procedure. Longer chain diols were found to be more reactive than the shorter chain alternatives, generally giving rise to higher molecular weight polymers, an effect shown to be most pronounced when using the transesterification route. Finally, novel diesters with high degrees of branching in their hydrocarbon chains are introduced as potential monomers for possible low surface energy materials applications.

Original languageEnglish (US)
Pages (from-to)61-77
Number of pages17
JournalFaraday Discussions
Volume202
DOIs
StatePublished - 2017

Fingerprint

Polyesters
polyesters
biomass
Biomass
Polymers
monomers
Monomers
Transesterification
acids
Pimelic Acids
Derivatives
Transition Temperature
Hydrocarbons
Interfacial energy
Polymerization
Glass
polymer chemistry
Chlorides
Molecular Weight
Chemical activation

ASJC Scopus subject areas

  • Medicine(all)
  • Physical and Theoretical Chemistry

Cite this

Arnaud, S. P., Wu, L., Wong Chang, M. A., Comerford, J. W., Farmer, T. J., Schmid, M., ... Mascal, M. (2017). New bio-based monomers: Tuneable polyester properties using branched diols from biomass. Faraday Discussions, 202, 61-77. https://doi.org/10.1039/c7fd00057j

New bio-based monomers : Tuneable polyester properties using branched diols from biomass. / Arnaud, Sacha Pérocheau; Wu, Linglin; Wong Chang, Maria Angelica; Comerford, James W.; Farmer, Thomas J.; Schmid, Maximilian; Chang, Fei; Li, Zheng; Mascal, Mark.

In: Faraday Discussions, Vol. 202, 2017, p. 61-77.

Research output: Contribution to journalArticle

Arnaud, SP, Wu, L, Wong Chang, MA, Comerford, JW, Farmer, TJ, Schmid, M, Chang, F, Li, Z & Mascal, M 2017, 'New bio-based monomers: Tuneable polyester properties using branched diols from biomass', Faraday Discussions, vol. 202, pp. 61-77. https://doi.org/10.1039/c7fd00057j
Arnaud, Sacha Pérocheau ; Wu, Linglin ; Wong Chang, Maria Angelica ; Comerford, James W. ; Farmer, Thomas J. ; Schmid, Maximilian ; Chang, Fei ; Li, Zheng ; Mascal, Mark. / New bio-based monomers : Tuneable polyester properties using branched diols from biomass. In: Faraday Discussions. 2017 ; Vol. 202. pp. 61-77.
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