The vibrational dynamics during and after b-ET in B-30, both for the 'solvent-controlled regime' as well as under conditions of a 'frozen' solvent, were studied. Modes were identified by resonance Raman spectra in the charge transfer absorption band. Vibrational excess populations were determined from time-resolved anti-Stokes Raman spectra. Thermal equilibrium between the Raman-active modes was established within 10 to 15 ps after b-ET.
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics