Abstract
The vibrational dynamics during and after b-ET in B-30, both for the 'solvent-controlled regime' as well as under conditions of a 'frozen' solvent, were studied. Modes were identified by resonance Raman spectra in the charge transfer absorption band. Vibrational excess populations were determined from time-resolved anti-Stokes Raman spectra. Thermal equilibrium between the Raman-active modes was established within 10 to 15 ps after b-ET.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1587-1594 |
| Number of pages | 8 |
| Journal | Journal of Chemical Physics |
| Volume | 113 |
| Issue number | 4 |
| DOIs | |
| State | Published - Jul 2000 |
| Externally published | Yes |
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Fingerprint Dive into the research topics of 'Mode-specific vibrational excitation and energy redistribution after ultrafast intramolecular electron transfer'. Together they form a unique fingerprint.
Cite this
Wachsmann-Hogiu, S., Werncke, W., Pfeiffer, M., Dreyer, J., & Elsaesser, T. (2000). Mode-specific vibrational excitation and energy redistribution after ultrafast intramolecular electron transfer. Journal of Chemical Physics, 113(4), 1587-1594. https://doi.org/10.1063/1.481946