Abstract
The vibrational dynamics during and after b-ET in B-30, both for the 'solvent-controlled regime' as well as under conditions of a 'frozen' solvent, were studied. Modes were identified by resonance Raman spectra in the charge transfer absorption band. Vibrational excess populations were determined from time-resolved anti-Stokes Raman spectra. Thermal equilibrium between the Raman-active modes was established within 10 to 15 ps after b-ET.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1587-1594 |
| Number of pages | 8 |
| Journal | Journal of Chemical Physics |
| Volume | 113 |
| Issue number | 4 |
| DOIs | |
| State | Published - Jul 2000 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
Mode-specific vibrational excitation and energy redistribution after ultrafast intramolecular electron transfer. / Wachsmann-Hogiu, Sebastian; Werncke, W.; Pfeiffer, M.; Dreyer, J.; Elsaesser, T.
In: Journal of Chemical Physics, Vol. 113, No. 4, 07.2000, p. 1587-1594.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Mode-specific vibrational excitation and energy redistribution after ultrafast intramolecular electron transfer
AU - Wachsmann-Hogiu, Sebastian
AU - Werncke, W.
AU - Pfeiffer, M.
AU - Dreyer, J.
AU - Elsaesser, T.
PY - 2000/7
Y1 - 2000/7
N2 - The vibrational dynamics during and after b-ET in B-30, both for the 'solvent-controlled regime' as well as under conditions of a 'frozen' solvent, were studied. Modes were identified by resonance Raman spectra in the charge transfer absorption band. Vibrational excess populations were determined from time-resolved anti-Stokes Raman spectra. Thermal equilibrium between the Raman-active modes was established within 10 to 15 ps after b-ET.
AB - The vibrational dynamics during and after b-ET in B-30, both for the 'solvent-controlled regime' as well as under conditions of a 'frozen' solvent, were studied. Modes were identified by resonance Raman spectra in the charge transfer absorption band. Vibrational excess populations were determined from time-resolved anti-Stokes Raman spectra. Thermal equilibrium between the Raman-active modes was established within 10 to 15 ps after b-ET.
UR - http://www.scopus.com/inward/record.url?scp=0034226454&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0034226454&partnerID=8YFLogxK
U2 - 10.1063/1.481946
DO - 10.1063/1.481946
M3 - Article
VL - 113
SP - 1587
EP - 1594
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 4
ER -