Mode-specific vibrational excitation and energy redistribution after ultrafast intramolecular electron transfer

Sebastian Wachsmann-Hogiu; W. Werncke; M. Pfeiffer; J. Dreyer; T. Elsaesser

doi:10.1063/1.481946

Mode-specific vibrational excitation and energy redistribution after ultrafast intramolecular electron transfer

Sebastian Wachsmann-Hogiu, W. Werncke, M. Pfeiffer, J. Dreyer, T. Elsaesser

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

The vibrational dynamics during and after b-ET in B-30, both for the 'solvent-controlled regime' as well as under conditions of a 'frozen' solvent, were studied. Modes were identified by resonance Raman spectra in the charge transfer absorption band. Vibrational excess populations were determined from time-resolved anti-Stokes Raman spectra. Thermal equilibrium between the Raman-active modes was established within 10 to 15 ps after b-ET.

Original language	English (US)
Pages (from-to)	1587-1594
Number of pages	8
Journal	Journal of Chemical Physics
Volume	113
Issue number	4
DOIs	https://doi.org/10.1063/1.481946
State	Published - Jul 2000
Externally published	Yes

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics

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10.1063/1.481946

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author = "Sebastian Wachsmann-Hogiu and W. Werncke and M. Pfeiffer and J. Dreyer and T. Elsaesser",

year = "2000",

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T1 - Mode-specific vibrational excitation and energy redistribution after ultrafast intramolecular electron transfer

AU - Wachsmann-Hogiu, Sebastian

AU - Werncke, W.

AU - Pfeiffer, M.

AU - Dreyer, J.

AU - Elsaesser, T.

PY - 2000/7

Y1 - 2000/7

N2 - The vibrational dynamics during and after b-ET in B-30, both for the 'solvent-controlled regime' as well as under conditions of a 'frozen' solvent, were studied. Modes were identified by resonance Raman spectra in the charge transfer absorption band. Vibrational excess populations were determined from time-resolved anti-Stokes Raman spectra. Thermal equilibrium between the Raman-active modes was established within 10 to 15 ps after b-ET.

AB - The vibrational dynamics during and after b-ET in B-30, both for the 'solvent-controlled regime' as well as under conditions of a 'frozen' solvent, were studied. Modes were identified by resonance Raman spectra in the charge transfer absorption band. Vibrational excess populations were determined from time-resolved anti-Stokes Raman spectra. Thermal equilibrium between the Raman-active modes was established within 10 to 15 ps after b-ET.

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ER -

Mode-specific vibrational excitation and energy redistribution after ultrafast intramolecular electron transfer

Abstract

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