Mode-specific vibrational excitation and energy redistribution after ultrafast intramolecular electron transfer

Sebastian Wachsmann-Hogiu, W. Werncke, M. Pfeiffer, J. Dreyer, T. Elsaesser

Research output: Contribution to journalArticle

26 Scopus citations

Abstract

The vibrational dynamics during and after b-ET in B-30, both for the 'solvent-controlled regime' as well as under conditions of a 'frozen' solvent, were studied. Modes were identified by resonance Raman spectra in the charge transfer absorption band. Vibrational excess populations were determined from time-resolved anti-Stokes Raman spectra. Thermal equilibrium between the Raman-active modes was established within 10 to 15 ps after b-ET.

Original languageEnglish (US)
Pages (from-to)1587-1594
Number of pages8
JournalJournal of Chemical Physics
Volume113
Issue number4
DOIs
StatePublished - Jul 2000
Externally publishedYes

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

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