Microphysics of aqueous droplets in clouds and fogs as applied to PM-fine modeling

Mohammed A. Majeed, Anthony S. Wexler

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Clouds and fogs transform atmospheric gases through gas- and liquid-phase chemistry, and cause the production of PM-fine aerosols. The aqueous-phase concentrations of pollutants in the clouds and fogs depend on gas-phase concentrations, their solubility, and mass transfer rates. Therefore, it is important to study cloud microphysics and dynamics to understand in what portions of an aerosol size distribution oxidation occurs during a supersaturation event, when and how it occurs, and as a result understand why chemical composition depends on droplet size. The growth rate of individual cloud condensation nuclei to cloud droplets is governed by the mass transfer equation which is traditionally expressed in terms of first moment change, i.e., rate of change of cloud droplet diameters. Since droplet aqueous chemistry is directly related to the liquid water mass, the third moment more fully elucidates their growth behavior. By viewing cloud activation in these terms, it is observed that some sections of the aerosol size distribution trade water thus limiting the time that a section may experience the aqueous chemistry. Three characteristic times explain the trading of water between different sections during the cloud's lifetime, and why transport to particles is fast or slow in different distributions.

Original languageEnglish (US)
Pages (from-to)1639-1653
Number of pages15
JournalAtmospheric Environment
Volume35
Issue number9
DOIs
StatePublished - 2001
Externally publishedYes

Fingerprint

Fog
fog
droplet
cloud droplet
modeling
mass transfer
particle size
Aerosols
cloud microphysics
liquid
cloud condensation nucleus
atmospheric gas
supersaturation
gas
water mass
solubility
transform
Mass transfer
chemical composition
Gases

Keywords

  • Aerosols
  • Clouds
  • Fogs
  • Microphysics
  • PM-fine

ASJC Scopus subject areas

  • Atmospheric Science
  • Environmental Science(all)
  • Pollution

Cite this

Microphysics of aqueous droplets in clouds and fogs as applied to PM-fine modeling. / Majeed, Mohammed A.; Wexler, Anthony S.

In: Atmospheric Environment, Vol. 35, No. 9, 2001, p. 1639-1653.

Research output: Contribution to journalArticle

Majeed, Mohammed A. ; Wexler, Anthony S. / Microphysics of aqueous droplets in clouds and fogs as applied to PM-fine modeling. In: Atmospheric Environment. 2001 ; Vol. 35, No. 9. pp. 1639-1653.
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