Knoevenagel condensations of β-hemiacetyl esters

Pilho Kim; Marilyn M. Olmstead; Michael H. Nantz; Mark J. Kurth

Knoevenagel condensations of β-hemiacetyl esters

Pilho Kim, Marilyn M. Olmstead, Michael H. Nantz, Mark J. Kurth

Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The intermolecular Knoevenagel condensation of β-hemiacetyl ester proceeds by an in situ unmasking of a reactive ω-hydroxy-β-keto ester giving unsaturated ω-hydroxy-β-keto esters 6-12 which accommodate acetal formation. (C) 2000 Elsevier Science Ltd.

Original language	English (US)
Pages (from-to)	4029-4032
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	21
State	Published - May 29 2000

Keywords

Acetal formation
Eleuthesides
Knoevenagel condensation

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Drug Discovery

Cite this

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title = "Knoevenagel condensations of β-hemiacetyl esters",

abstract = "The intermolecular Knoevenagel condensation of β-hemiacetyl ester proceeds by an in situ unmasking of a reactive ω-hydroxy-β-keto ester giving unsaturated ω-hydroxy-β-keto esters 6-12 which accommodate acetal formation. (C) 2000 Elsevier Science Ltd.",

keywords = "Acetal formation, Eleuthesides, Knoevenagel condensation",

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AU - Kim, Pilho

AU - Olmstead, Marilyn M.

AU - Nantz, Michael H.

AU - Kurth, Mark J.

PY - 2000/5/29

Y1 - 2000/5/29

N2 - The intermolecular Knoevenagel condensation of β-hemiacetyl ester proceeds by an in situ unmasking of a reactive ω-hydroxy-β-keto ester giving unsaturated ω-hydroxy-β-keto esters 6-12 which accommodate acetal formation. (C) 2000 Elsevier Science Ltd.

AB - The intermolecular Knoevenagel condensation of β-hemiacetyl ester proceeds by an in situ unmasking of a reactive ω-hydroxy-β-keto ester giving unsaturated ω-hydroxy-β-keto esters 6-12 which accommodate acetal formation. (C) 2000 Elsevier Science Ltd.

KW - Acetal formation

KW - Eleuthesides

KW - Knoevenagel condensation

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M3 - Article

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 21

ER -

Knoevenagel condensations of β-hemiacetyl esters

Abstract

Keywords

ASJC Scopus subject areas

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