Indoor residence times of semivolatile organic compounds: Model estimation and field evaluation

Hyeong Moo Shin, Thomas E. McKone, Nicolle S. Tulve, Matthew S. Clifton, Deborah H Bennett

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Indoor residence times of semivolatile organic compounds (SVOCs) are a major and mostly unavailable input for residential exposure assessment. We calculated residence times for a suite of SVOCs using a fugacity model applied to residential environments. Residence times depend on both the mass distribution of the compound between the "mobile phase" (air and dust particles settled on the carpet) and the "non-mobile phase" (carpet fibers and pad) and the removal rates resulting from air exchange and cleaning. We estimated dust removal rates from cleaning processes using an indoor-particle mass-balance model. Chemical properties determine both the mass distribution and relative importance of the two removal pathways, resulting in different residence times among compounds. We conducted a field study after chlorpyrifos was phased out for indoor use in the United States in 2001 to determine the decreases in chlorpyrifos air concentrations over a one-year period. A measured average decrease of 18% in chlorpyrifos air concentrations indicates the residence time of chlorpyrifos is expected to be 6.9 years and compares well with model predictions. The estimates from this study provide the opportunity to make more reliable estimates of SVOCs exposure in the indoor residential environment.

Original languageEnglish (US)
Pages (from-to)859-867
Number of pages9
JournalEnvironmental Science and Technology
Volume47
Issue number2
DOIs
StatePublished - Jan 15 2013

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Chlorpyrifos
Organic compounds
chlorpyrifos
residence time
organic compound
Air
Dust
air
Cleaning
Chemical properties
Particles (particulate matter)
fugacity
chemical property
mass balance
evaluation
Fibers
dust
prediction

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry

Cite this

Indoor residence times of semivolatile organic compounds : Model estimation and field evaluation. / Shin, Hyeong Moo; McKone, Thomas E.; Tulve, Nicolle S.; Clifton, Matthew S.; Bennett, Deborah H.

In: Environmental Science and Technology, Vol. 47, No. 2, 15.01.2013, p. 859-867.

Research output: Contribution to journalArticle

Shin, Hyeong Moo ; McKone, Thomas E. ; Tulve, Nicolle S. ; Clifton, Matthew S. ; Bennett, Deborah H. / Indoor residence times of semivolatile organic compounds : Model estimation and field evaluation. In: Environmental Science and Technology. 2013 ; Vol. 47, No. 2. pp. 859-867.
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