In situ and real-time atomic force microscopy studies of the stability of oligothiophene langmuir-blodgett monolayers in liquid

Nai Ning Yin, Alexander Buyanin, Shawn L. Riechers, Olivia P. Lee, Jean M J Fréchet, Miquel Salmeron, Gang-yu Liu

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Oligothiophene thin films have been considered as promising material for molecular electronics due to their desirable electronic properties and high structural stability under ambient conditions. To ensure performance in devices the functional structures, such as individual ordered domains, must be stable under practical and operational conditions or environments including exposure to various media. This work investigates the structure of oligothiophene Langmuir-Blodgett (LB) films upon exposure to liquid media such as water, ethanol (EtOH), and mixed tetrahydrofuran (THF)/EtOH solutions. The LB films form islands ranging from 500 nm up to 1 μm consisting of densely packed oligothiophene molecules. These islands are surrounded by bare substrate and loosely packed adsorbates. In situ and time-dependent AFM images were acquired to reveal the structural evolution, from which degradation pathways and kinetics are extracted. Degradation of these LB films initiates and propagates from intraisland defect sites, such as cracks and pin holes, whereas the edges of islands remain intact on the surface. The observations appear to be in contrast to the known degradation mechanism among self-assembled monolayers, such as alkanethiols on gold, which initiates and progresses at domain boundaries. Rationale for the observed degradation processes will also be discussed.

Original languageEnglish (US)
Pages (from-to)5789-5795
Number of pages7
JournalJournal of Physical Chemistry C
Volume118
Issue number11
DOIs
StatePublished - Mar 20 2014

Fingerprint

Langmuir Blodgett films
Monolayers
Atomic force microscopy
Langmuir-Blodgett films
atomic force microscopy
degradation
Degradation
Liquids
liquids
Molecular electronics
molecular electronics
structural stability
Self assembled monolayers
Adsorbates
tetrahydrofuran
Gold
Electronic properties
Ethanol
ethyl alcohol
cracks

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

In situ and real-time atomic force microscopy studies of the stability of oligothiophene langmuir-blodgett monolayers in liquid. / Yin, Nai Ning; Buyanin, Alexander; Riechers, Shawn L.; Lee, Olivia P.; Fréchet, Jean M J; Salmeron, Miquel; Liu, Gang-yu.

In: Journal of Physical Chemistry C, Vol. 118, No. 11, 20.03.2014, p. 5789-5795.

Research output: Contribution to journalArticle

Yin, Nai Ning ; Buyanin, Alexander ; Riechers, Shawn L. ; Lee, Olivia P. ; Fréchet, Jean M J ; Salmeron, Miquel ; Liu, Gang-yu. / In situ and real-time atomic force microscopy studies of the stability of oligothiophene langmuir-blodgett monolayers in liquid. In: Journal of Physical Chemistry C. 2014 ; Vol. 118, No. 11. pp. 5789-5795.
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