Abstract
An efficient, stereoselective synthesis of octahydro-as-indacenone 2, the carbocycle fragment of the antibiotic ikarugamycin, is described. The prominent step in this sequence is an intramolecular Diels-Alder reaction, which establishes the relative stereochemistry of 2.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 731-733 |
| Number of pages | 3 |
| Journal | Journal of Organic Chemistry |
| Volume | 49 |
| Issue number | 4 |
| State | Published - 1984 |
ASJC Scopus subject areas
- Organic Chemistry
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Cite this
Kurth, M. J., Burns, D. H., & O'Brien, M. J. (1984). Ikarugamycin: Total synthesis of the decahydro-as-indacene portion. Journal of Organic Chemistry, 49(4), 731-733.