Highly efficient synthesis and inclusion properties of star-shaped amphiphilic derivatives of cholic acid

Juntao Luo; Yilong Chen; X. X. Zhu

doi:10.1055/s-2007-984909

Highly efficient synthesis and inclusion properties of star-shaped amphiphilic derivatives of cholic acid

Juntao Luo, Yilong Chen, X. X. Zhu

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

New star-shaped cholic acid derivatives with different functional groups have been synthesized by the use of Cu¹-catalyzed [2+3] cyclization (click chemistry) and Curtius rearrangement of acyl azide intermediate in good yields. We have also studied the solution properties of these star-shaped amphiphilic compounds as host molecules to interact with nonpolar guest molecules by the use of fluorescent probes.

Original language	English (US)
Pages (from-to)	2201-2204
Number of pages	4
Journal	Synlett
Issue number	14
DOIs	https://doi.org/10.1055/s-2007-984909
State	Published - Sep 3 2007
Externally published	Yes

Keywords

Conjugation
Host-guest systems
Oligomerization
Steroids
Supermolecular chemistry

ASJC Scopus subject areas

Organic Chemistry

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abstract = "New star-shaped cholic acid derivatives with different functional groups have been synthesized by the use of Cu1-catalyzed [2+3] cyclization (click chemistry) and Curtius rearrangement of acyl azide intermediate in good yields. We have also studied the solution properties of these star-shaped amphiphilic compounds as host molecules to interact with nonpolar guest molecules by the use of fluorescent probes.",

keywords = "Conjugation, Host-guest systems, Oligomerization, Steroids, Supermolecular chemistry",

author = "Juntao Luo and Yilong Chen and Zhu, {X. X.}",

year = "2007",

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doi = "10.1055/s-2007-984909",

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AU - Luo, Juntao

AU - Chen, Yilong

AU - Zhu, X. X.

PY - 2007/9/3

Y1 - 2007/9/3

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AB - New star-shaped cholic acid derivatives with different functional groups have been synthesized by the use of Cu1-catalyzed [2+3] cyclization (click chemistry) and Curtius rearrangement of acyl azide intermediate in good yields. We have also studied the solution properties of these star-shaped amphiphilic compounds as host molecules to interact with nonpolar guest molecules by the use of fluorescent probes.

KW - Conjugation

KW - Host-guest systems

KW - Oligomerization

KW - Steroids

KW - Supermolecular chemistry

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Highly efficient synthesis and inclusion properties of star-shaped amphiphilic derivatives of cholic acid

Abstract

Keywords

ASJC Scopus subject areas

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