Hidden role of trace gas impurities in chemical vapor deposition growth of vertically-aligned carbon nanotube arrays

Jung Bin In; Costas P. Grigoropoulos; Alexander A. Chernov; Aleksandr Noy

doi:10.1063/1.3573830

Hidden role of trace gas impurities in chemical vapor deposition growth of vertically-aligned carbon nanotube arrays

Jung Bin In, Costas P. Grigoropoulos, Alexander A. Chernov, Aleksandr Noy

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Carbon nanotubes (CNTs) grow in a seemingly simple catalytic chemical vapor deposition (CVD) process, yet the detailed mechanism of the process has continued to puzzle researchers. We have examined the role of trace amounts of gas impurities on the kinetics of atmospheric pressure CVD growth of CNTs. Our studies, which used an in situ height monitoring system, revealed that even the nominally ultrapure gases contain enough trace amounts of oxygen-containing species to affect the growth drastically. We were able to obtain the "clean" kinetics of the CNT array growth by passing the feed gases through the high performance gas purifiers. Our data show a remarkable decrease in the catalytic lifetime after the removal of the trace oxygen containing impurities. We suggest that the gas purification is an essential step in obtaining reliable nanotube growth data.

Original language	English (US)
Article number	153102
Journal	Applied Physics Letters
Volume	98
Issue number	15
DOIs	https://doi.org/10.1063/1.3573830
State	Published - Apr 11 2011
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy (miscellaneous)

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abstract = "Carbon nanotubes (CNTs) grow in a seemingly simple catalytic chemical vapor deposition (CVD) process, yet the detailed mechanism of the process has continued to puzzle researchers. We have examined the role of trace amounts of gas impurities on the kinetics of atmospheric pressure CVD growth of CNTs. Our studies, which used an in situ height monitoring system, revealed that even the nominally ultrapure gases contain enough trace amounts of oxygen-containing species to affect the growth drastically. We were able to obtain the {"}clean{"} kinetics of the CNT array growth by passing the feed gases through the high performance gas purifiers. Our data show a remarkable decrease in the catalytic lifetime after the removal of the trace oxygen containing impurities. We suggest that the gas purification is an essential step in obtaining reliable nanotube growth data.",

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AU - Grigoropoulos, Costas P.

AU - Chernov, Alexander A.

AU - Noy, Aleksandr

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AB - Carbon nanotubes (CNTs) grow in a seemingly simple catalytic chemical vapor deposition (CVD) process, yet the detailed mechanism of the process has continued to puzzle researchers. We have examined the role of trace amounts of gas impurities on the kinetics of atmospheric pressure CVD growth of CNTs. Our studies, which used an in situ height monitoring system, revealed that even the nominally ultrapure gases contain enough trace amounts of oxygen-containing species to affect the growth drastically. We were able to obtain the "clean" kinetics of the CNT array growth by passing the feed gases through the high performance gas purifiers. Our data show a remarkable decrease in the catalytic lifetime after the removal of the trace oxygen containing impurities. We suggest that the gas purification is an essential step in obtaining reliable nanotube growth data.

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Hidden role of trace gas impurities in chemical vapor deposition growth of vertically-aligned carbon nanotube arrays

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