Formation and detection of neutral FeCHx (x = 0-3) using neutralization-reionization mass spectrometry (NRMS)

Carlito B Lebrilla; Thomas Drewello; Helmut Schwarz

Formation and detection of neutral FeCH_x (x = 0-3) using neutralization-reionization mass spectrometry (NRMS)

Carlito B Lebrilla, Thomas Drewello, Helmut Schwarz

Research output: Contribution to journal › Article › peer-review

Abstract

Neutralization-reionization mass spectrometry (NRMS) has been used for the first time to generate and characterize in the gas phase neutral FeCH_x (x = 0-3). Evidence is presented that neither ionic FeCH_x ⁺ (x = 0, 2, 3) nor its neutral analogue FeCH_x (x = 0, 2, 3) rearranges to hydridometal complexes HFeCH_x (x = 1, 2), in contrast to FeCH⁺/FeCH which rearranges to HFeC⁺ and HFeC, respectively.

Original language	English (US)
Pages (from-to)	2268-2270
Number of pages	3
Journal	Organometallics
Volume	6
Issue number	10
State	Published - 1987
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry
Organic Chemistry

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title = "Formation and detection of neutral FeCHx (x = 0-3) using neutralization-reionization mass spectrometry (NRMS)",

abstract = "Neutralization-reionization mass spectrometry (NRMS) has been used for the first time to generate and characterize in the gas phase neutral FeCHx (x = 0-3). Evidence is presented that neither ionic FeCHx + (x = 0, 2, 3) nor its neutral analogue FeCHx (x = 0, 2, 3) rearranges to hydridometal complexes HFeCHx (x = 1, 2), in contrast to FeCH+/FeCH which rearranges to HFeC+ and HFeC, respectively.",

author = "Lebrilla, {Carlito B} and Thomas Drewello and Helmut Schwarz",

year = "1987",

language = "English (US)",

volume = "6",

pages = "2268--2270",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - Formation and detection of neutral FeCHx (x = 0-3) using neutralization-reionization mass spectrometry (NRMS)

AU - Lebrilla, Carlito B

AU - Drewello, Thomas

AU - Schwarz, Helmut

PY - 1987

Y1 - 1987

N2 - Neutralization-reionization mass spectrometry (NRMS) has been used for the first time to generate and characterize in the gas phase neutral FeCHx (x = 0-3). Evidence is presented that neither ionic FeCHx + (x = 0, 2, 3) nor its neutral analogue FeCHx (x = 0, 2, 3) rearranges to hydridometal complexes HFeCHx (x = 1, 2), in contrast to FeCH+/FeCH which rearranges to HFeC+ and HFeC, respectively.

AB - Neutralization-reionization mass spectrometry (NRMS) has been used for the first time to generate and characterize in the gas phase neutral FeCHx (x = 0-3). Evidence is presented that neither ionic FeCHx + (x = 0, 2, 3) nor its neutral analogue FeCHx (x = 0, 2, 3) rearranges to hydridometal complexes HFeCHx (x = 1, 2), in contrast to FeCH+/FeCH which rearranges to HFeC+ and HFeC, respectively.

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M3 - Article

AN - SCOPUS:0008350155

VL - 6

SP - 2268

EP - 2270

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 10

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