Formation and detection of neutral FeCHx (x = 0-3) using neutralization-reionization mass spectrometry (NRMS)

Carlito B Lebrilla, Thomas Drewello, Helmut Schwarz

Research output: Contribution to journalArticle

30 Scopus citations

Abstract

Neutralization-reionization mass spectrometry (NRMS) has been used for the first time to generate and characterize in the gas phase neutral FeCHx (x = 0-3). Evidence is presented that neither ionic FeCHx + (x = 0, 2, 3) nor its neutral analogue FeCHx (x = 0, 2, 3) rearranges to hydridometal complexes HFeCHx (x = 1, 2), in contrast to FeCH+/FeCH which rearranges to HFeC+ and HFeC, respectively.

Original languageEnglish (US)
Pages (from-to)2268-2270
Number of pages3
JournalOrganometallics
Volume6
Issue number10
StatePublished - 1987
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

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