Fluoride-selective host based on anion-π interactions, ion pairing, and hydrogen bonding: Synthesis and fluoride-ion sandwich complex

Mark Mascal; Ilya Yakovlev; Edward B. Nikitin; James C. Fettinger

doi:10.1002/anie.200704005

Fluoride-selective host based on anion-π interactions, ion pairing, and hydrogen bonding: Synthesis and fluoride-ion sandwich complex

Mark Mascal, Ilya Yakovlev, Edward B. Nikitin, James C. Fettinger

Chemistry

Research output: Contribution to journal › Article › peer-review

148 Scopus citations

Abstract

A fluoride sandwich: A cylindrophane macrocycle framed with cyanuric acid rings selectively complexes fluoride ion by a combination of anion-π interactions and ion-pair-reinforced hydrogen bonds. This compound is the first example of a purpose-designed host that exploits anion-π bonding. (Chemical Equation Presented).

Original language	English (US)
Pages (from-to)	8782-8784
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	46
DOIs	https://doi.org/10.1002/anie.200704005
State	Published - 2007

Keywords

Anion-π interactions
Cyclophanes
Fluorides
Host-guest systems
Hydrogen bonds

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1002/anie.200704005

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AU - Nikitin, Edward B.

AU - Fettinger, James C.

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KW - Cyclophanes

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KW - Host-guest systems

KW - Hydrogen bonds

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