Abstract
A fluoride sandwich: A cylindrophane macrocycle framed with cyanuric acid rings selectively complexes fluoride ion by a combination of anion-π interactions and ion-pair-reinforced hydrogen bonds. This compound is the first example of a purpose-designed host that exploits anion-π bonding. (Chemical Equation Presented).
| Original language | English (US) |
|---|---|
| Pages (from-to) | 8782-8784 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 46 |
| Issue number | 46 |
| DOIs | |
| State | Published - 2007 |
Keywords
- Anion-π interactions
- Cyclophanes
- Fluorides
- Host-guest systems
- Hydrogen bonds
ASJC Scopus subject areas
- Chemistry(all)
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Mascal, M., Yakovlev, I., Nikitin, E. B., & Fettinger, J. C. (2007). Fluoride-selective host based on anion-π interactions, ion pairing, and hydrogen bonding: Synthesis and fluoride-ion sandwich complex. Angewandte Chemie - International Edition, 46(46), 8782-8784. https://doi.org/10.1002/anie.200704005