Facile synthesis of germanium nanoparticles with size control: Microwave versus conventional heating

Elayaraja Muthuswamy, Andrew S. Iskandar, Marlene M. Amador, Susan M. Kauzlarich

Research output: Contribution to journalArticle

62 Citations (Scopus)

Abstract

A facile size-controlled synthesis (microwave/conventional) of quasi-spherical germanium nanoparticles is reported. Oleylamine serves as a solvent, a binding ligand, and a reducing agent in the synthesis. Reactions were carried out with microwave-assisted heating, and the results have been compared with those produced by conventional heating. Germanium iodides (GeI 4, GeI2) were used as the Ge precursor, and size control in the range of 4-11 nm was achieved by controlling the ratio of Ge 4+/Ge2+ in the precursor mix. Longer reaction times and higher temperatures were also observed to have an effect on the nanoparticle size distribution. Microwave heating resulted in crystalline nanoparticles at lower temperatures than conventional resistive heating because of the ability of germanium iodides to convert electromagnetic radiation directly to heat. The reported approach for germanium nanoparticle preparation avoids the use of strong reducing agents (LiAlH4, n-BuLi, NaBH4) and HF for etching and, thus, can be considered simple, safe, and amenable to industrial-level scaleup. The as-prepared nanoparticles are a stable dispersion (hexane or toluene) for weeks when stored under an inert atmosphere (N 2/Ar). The stability of the colloidal dispersion was observed to be dependent on the nanoparticle size, with smaller nanoparticles exhibiting longer stability. On exposure to ambient conditions, oxidation occurs over a period of time and results in slow precipitation of the nanoparticles. The nanoparticles have been characterized by powder X-ray diffraction (PXRD), transmission electron microscopy (TEM), and spectroscopic techniques (UV-Vis-NIR, FTIR, Raman).

Original languageEnglish (US)
Pages (from-to)1416-1422
Number of pages7
JournalChemistry of Materials
Volume25
Issue number8
DOIs
StatePublished - Apr 23 2013

Fingerprint

Germanium
Microwaves
Nanoparticles
Heating
Reducing Agents
Iodides
Reducing agents
Microwave heating
Toluene
Hexanes
Hexane
Electromagnetic waves
X ray powder diffraction
Etching
Ligands
Crystalline materials
Transmission electron microscopy
Oxidation
Temperature

Keywords

  • germanium nanocrystals
  • microwave synthesis
  • size control

ASJC Scopus subject areas

  • Materials Chemistry
  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Facile synthesis of germanium nanoparticles with size control : Microwave versus conventional heating. / Muthuswamy, Elayaraja; Iskandar, Andrew S.; Amador, Marlene M.; Kauzlarich, Susan M.

In: Chemistry of Materials, Vol. 25, No. 8, 23.04.2013, p. 1416-1422.

Research output: Contribution to journalArticle

Muthuswamy, Elayaraja ; Iskandar, Andrew S. ; Amador, Marlene M. ; Kauzlarich, Susan M. / Facile synthesis of germanium nanoparticles with size control : Microwave versus conventional heating. In: Chemistry of Materials. 2013 ; Vol. 25, No. 8. pp. 1416-1422.
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