Eu14MnSb11, a novel rare earth metal Zintl compound

Anette Rehr; Susan M. Kauzlarich

doi:10.1016/0925-8388(94)90255-0

Eu₁₄MnSb₁₁, a novel rare earth metal Zintl compound

Anette Rehr, Susan M. Kauzlarich

Chemistry

Research output: Contribution to journal › Article

39 Scopus citations

Abstract

A new rare earth metal Zintl compound, Eu₁₄MnSb₁₁, has been prepared in high yield from reacting stoichiometric amounts of the elements in a sealed tantalum tube, sealed in a quartz ampoule, at 1250 °C for 24 h. Eu₁₄MnSb₁₁ is isostructural with the Zintl compounds A₁₄MPn₁₁ (A = Ca, Sr, Ba; M = Al, Ga, Mn; Pn = As, Sb, Bi). Single crystal X-ray diffraction shows that this compound crystallizes in the tetragonal space group I4₁/acd, a = 17.300(3) A ̊, c = 22.746(4) A ̊, T = 130 K, Z = 8.

Original language	English (US)
Pages (from-to)	424-426
Number of pages	3
Journal	Journal of Alloys and Compounds
Volume	207-208
Issue number	C
DOIs	https://doi.org/10.1016/0925-8388(94)90255-0
State	Published - 1994

ASJC Scopus subject areas

Metals and Alloys

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Rehr, A., & Kauzlarich, S. M. (1994). Eu₁₄MnSb₁₁, a novel rare earth metal Zintl compound. Journal of Alloys and Compounds, 207-208(C), 424-426. https://doi.org/10.1016/0925-8388(94)90255-0

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abstract = "A new rare earth metal Zintl compound, Eu14MnSb11, has been prepared in high yield from reacting stoichiometric amounts of the elements in a sealed tantalum tube, sealed in a quartz ampoule, at 1250 °C for 24 h. Eu14MnSb11 is isostructural with the Zintl compounds A14MPn11 (A = Ca, Sr, Ba; M = Al, Ga, Mn; Pn = As, Sb, Bi). Single crystal X-ray diffraction shows that this compound crystallizes in the tetragonal space group I41/acd, a = 17.300(3) A ̊, c = 22.746(4) A ̊, T = 130 K, Z = 8.",

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AB - A new rare earth metal Zintl compound, Eu14MnSb11, has been prepared in high yield from reacting stoichiometric amounts of the elements in a sealed tantalum tube, sealed in a quartz ampoule, at 1250 °C for 24 h. Eu14MnSb11 is isostructural with the Zintl compounds A14MPn11 (A = Ca, Sr, Ba; M = Al, Ga, Mn; Pn = As, Sb, Bi). Single crystal X-ray diffraction shows that this compound crystallizes in the tetragonal space group I41/acd, a = 17.300(3) A ̊, c = 22.746(4) A ̊, T = 130 K, Z = 8.

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