Abstract
The high temperature p-type thermoelectric material Yb 14MnSb 11 has been of increasing research interest since its high temperature thermoelectric properties were first measured in 2006. Subsequent substitutions of Zn, Al, and La into the structure have shown that this material can be further optimized by altering the carrier concentration or by reduction of spin-disorder scattering. Here the properties of the Yb 14-xCa xMnSb 11 solid solution series where isovalent Ca 2+ is substituted for Yb 2+ will be presented. Crystals of the Yb 14-xCa xMnSb 11 solid solution series were made by Sn-flux (x = 2, 4, 6, 8) with the following ratio of elements: (14-x)Yb: xCa: 6 Mn: 11Sb: 86Sn, and their structures determined by single crystal X-ray diffraction. The density of the material significantly decreases by over 2 g/cm 3 as more Ca is added (from x = 1 to 8), because of the lighter mass of Ca. The resulting lower density is beneficial from a device manufacturing perspective where there is often a trade-off with the specific power per kilogram. The compounds crystallize in the Ca 14AlSb 11 structure type. The Ca substitution contributes to systematic lengthening the Mn-Sb bond while shortening the Sb-Sb bond in the 3 atom linear unit with increasing amounts of Ca. Temperature dependent thermoelectric properties, Seebeck, electrical resistivity, and thermal conductivity were measured from room temperature to 1273 K. Substitution of Yb with Ca improves the Seebeck coefficient while decreasing the thermal conductivity, along with decreasing the carrier concentration in this p-type material resulting in an enhanced thermoelectric figure of merit, zT, compared to Yb 14MnSb 11.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 7617-7624 |
| Number of pages | 8 |
| Journal | Inorganic Chemistry |
| Volume | 51 |
| Issue number | 14 |
| DOIs | |
| State | Published - Jul 16 2012 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
Cite this
Enhanced high-temperature thermoelectric performance of Yb 14-xCa xMnSb 11 . / Uvarov, Catherine A.; Ortega-Alvarez, Francisco; Kauzlarich, Susan M.
In: Inorganic Chemistry, Vol. 51, No. 14, 16.07.2012, p. 7617-7624.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Enhanced high-temperature thermoelectric performance of Yb 14-xCa xMnSb 11
AU - Uvarov, Catherine A.
AU - Ortega-Alvarez, Francisco
AU - Kauzlarich, Susan M.
PY - 2012/7/16
Y1 - 2012/7/16
N2 - The high temperature p-type thermoelectric material Yb 14MnSb 11 has been of increasing research interest since its high temperature thermoelectric properties were first measured in 2006. Subsequent substitutions of Zn, Al, and La into the structure have shown that this material can be further optimized by altering the carrier concentration or by reduction of spin-disorder scattering. Here the properties of the Yb 14-xCa xMnSb 11 solid solution series where isovalent Ca 2+ is substituted for Yb 2+ will be presented. Crystals of the Yb 14-xCa xMnSb 11 solid solution series were made by Sn-flux (x = 2, 4, 6, 8) with the following ratio of elements: (14-x)Yb: xCa: 6 Mn: 11Sb: 86Sn, and their structures determined by single crystal X-ray diffraction. The density of the material significantly decreases by over 2 g/cm 3 as more Ca is added (from x = 1 to 8), because of the lighter mass of Ca. The resulting lower density is beneficial from a device manufacturing perspective where there is often a trade-off with the specific power per kilogram. The compounds crystallize in the Ca 14AlSb 11 structure type. The Ca substitution contributes to systematic lengthening the Mn-Sb bond while shortening the Sb-Sb bond in the 3 atom linear unit with increasing amounts of Ca. Temperature dependent thermoelectric properties, Seebeck, electrical resistivity, and thermal conductivity were measured from room temperature to 1273 K. Substitution of Yb with Ca improves the Seebeck coefficient while decreasing the thermal conductivity, along with decreasing the carrier concentration in this p-type material resulting in an enhanced thermoelectric figure of merit, zT, compared to Yb 14MnSb 11.
AB - The high temperature p-type thermoelectric material Yb 14MnSb 11 has been of increasing research interest since its high temperature thermoelectric properties were first measured in 2006. Subsequent substitutions of Zn, Al, and La into the structure have shown that this material can be further optimized by altering the carrier concentration or by reduction of spin-disorder scattering. Here the properties of the Yb 14-xCa xMnSb 11 solid solution series where isovalent Ca 2+ is substituted for Yb 2+ will be presented. Crystals of the Yb 14-xCa xMnSb 11 solid solution series were made by Sn-flux (x = 2, 4, 6, 8) with the following ratio of elements: (14-x)Yb: xCa: 6 Mn: 11Sb: 86Sn, and their structures determined by single crystal X-ray diffraction. The density of the material significantly decreases by over 2 g/cm 3 as more Ca is added (from x = 1 to 8), because of the lighter mass of Ca. The resulting lower density is beneficial from a device manufacturing perspective where there is often a trade-off with the specific power per kilogram. The compounds crystallize in the Ca 14AlSb 11 structure type. The Ca substitution contributes to systematic lengthening the Mn-Sb bond while shortening the Sb-Sb bond in the 3 atom linear unit with increasing amounts of Ca. Temperature dependent thermoelectric properties, Seebeck, electrical resistivity, and thermal conductivity were measured from room temperature to 1273 K. Substitution of Yb with Ca improves the Seebeck coefficient while decreasing the thermal conductivity, along with decreasing the carrier concentration in this p-type material resulting in an enhanced thermoelectric figure of merit, zT, compared to Yb 14MnSb 11.
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UR - http://www.scopus.com/inward/citedby.url?scp=84863922720&partnerID=8YFLogxK
U2 - 10.1021/ic300567c
DO - 10.1021/ic300567c
M3 - Article
C2 - 22755507
AN - SCOPUS:84863922720
VL - 51
SP - 7617
EP - 7624
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 14
ER -