Electrochemical synthesis and characterization of NaCuO 2

Gerald L. Roberts, Susan M. Kauzlarich

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

NaCuO 2 has been prepared via electrodeposition from a sodium hydroxide/potassium hydroxide melt and characterized by single crystal and powder X-ray diffraction, magnetic susceptibility, and resistivity. Clusters of blue-black plate-like and needle crystals are grown at positive potentials on a platinum anode with a platinum or a zirconium crucible serving as the cathode and a platinum reference electrode. Details of the electrochemical procedure are described, along with a cyclic voltammogram. NaCuO 2 exhibits temperature independent paramagnetism over the temperature range 30 - 300 K. Its room temperature resistivity is greater than 10 6 Ω-cm.

Original languageEnglish (US)
Title of host publicationMaterials Research Society Symposium - Proceedings
PublisherMaterials Research Society
Pages457-461
Number of pages5
Volume346
StatePublished - 1994
EventProceedings of the 1994 MRS Spring Meeting - San Francisco, CA, USA
Duration: Apr 4 1994Apr 8 1994

Other

OtherProceedings of the 1994 MRS Spring Meeting
CitySan Francisco, CA, USA
Period4/4/944/8/94

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

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    Roberts, G. L., & Kauzlarich, S. M. (1994). Electrochemical synthesis and characterization of NaCuO 2 In Materials Research Society Symposium - Proceedings (Vol. 346, pp. 457-461). Materials Research Society.