Dithia Dications from Cyclic and Acyclic Precursors by Gas‐Phase Oxidation (“Charge Stripping”) of 3e/2c‐Radical Cations

Thomas Drewello, Carlito B Lebrilla, Klaus‐Dieter ‐D Asmus, Helmut Schwarz

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

What cannot be accomplished in solution is readily achieved in the gas phase by “charge‐stripping” mass spectrometry: generation of dications from radical cations of acyclic thioethers (e.g., 1 → 2). Ionization energies for the oxidation are in good agreement with the predictions of qualitative MO treatments of the bonding in three‐electron two‐center radical cations. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)1275-1276
Number of pages2
JournalAngewandte Chemie - International Edition
Volume28
Issue number9
DOIs
StatePublished - 1989
Externally publishedYes

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Cations
Positive ions
Oxidation
Ionization potential
Sulfides
Mass spectrometry
Gases

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Dithia Dications from Cyclic and Acyclic Precursors by Gas‐Phase Oxidation (“Charge Stripping”) of 3e/2c‐Radical Cations. / Drewello, Thomas; Lebrilla, Carlito B; Asmus, Klaus‐Dieter ‐D; Schwarz, Helmut.

In: Angewandte Chemie - International Edition, Vol. 28, No. 9, 1989, p. 1275-1276.

Research output: Contribution to journalArticle

Drewello, Thomas ; Lebrilla, Carlito B ; Asmus, Klaus‐Dieter ‐D ; Schwarz, Helmut. / Dithia Dications from Cyclic and Acyclic Precursors by Gas‐Phase Oxidation (“Charge Stripping”) of 3e/2c‐Radical Cations. In: Angewandte Chemie - International Edition. 1989 ; Vol. 28, No. 9. pp. 1275-1276.
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