TY - JOUR
T1 - Dichlorobis(triphenylphosphine oxide)magnesium
AU - Kucera, Benjamin E.
AU - Olmstead, Marilyn M.
AU - Tanke, Robin S.
AU - Kauzlarich, Susan M.
PY - 2003/6
Y1 - 2003/6
N2 - The compound [MgCl2(C18H15OP)2] was inadvertantly crystallized during a reaction involving magnesium germanide. It is isostructural to the Mn, Co, Cu and Zn analogs. Since four-coordinate Mg is rare, its structure is reported here. The Mg atom lies on a twofold axis and is surrounded by two O atoms and two Cl atoms in a distorted tetrahedral coordination geometry.
AB - The compound [MgCl2(C18H15OP)2] was inadvertantly crystallized during a reaction involving magnesium germanide. It is isostructural to the Mn, Co, Cu and Zn analogs. Since four-coordinate Mg is rare, its structure is reported here. The Mg atom lies on a twofold axis and is surrounded by two O atoms and two Cl atoms in a distorted tetrahedral coordination geometry.
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U2 - 10.1107/S1600536803009723
DO - 10.1107/S1600536803009723
M3 - Article
AN - SCOPUS:18444382055
VL - 59
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 6
ER -