Dichlorobis(triphenylphosphine oxide)magnesium

Benjamin E. Kucera; Marilyn M. Olmstead; Robin S. Tanke; Susan M. Kauzlarich

doi:10.1107/S1600536803009723

Dichlorobis(triphenylphosphine oxide)magnesium

Benjamin E. Kucera, Marilyn M. Olmstead, Robin S. Tanke, Susan M. Kauzlarich

Chemistry

Research output: Contribution to journal › Article

2 Scopus citations

Abstract

The compound [MgCl₂(C₁₈H₁₅OP)₂] was inadvertantly crystallized during a reaction involving magnesium germanide. It is isostructural to the Mn, Co, Cu and Zn analogs. Since four-coordinate Mg is rare, its structure is reported here. The Mg atom lies on a twofold axis and is surrounded by two O atoms and two Cl atoms in a distorted tetrahedral coordination geometry.

Original language	English (US)
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	6
DOIs	https://doi.org/10.1107/S1600536803009723
State	Published - Jun 2003

ASJC Scopus subject areas

Condensed Matter Physics
Structural Biology

Access to Document

10.1107/S1600536803009723

Fingerprint Dive into the research topics of 'Dichlorobis(triphenylphosphine oxide)magnesium'. Together they form a unique fingerprint.

Cite this

@article{b99d5036d6ab48e0b900b11789f0277e,

title = "Dichlorobis(triphenylphosphine oxide)magnesium",

abstract = "The compound [MgCl2(C18H15OP)2] was inadvertantly crystallized during a reaction involving magnesium germanide. It is isostructural to the Mn, Co, Cu and Zn analogs. Since four-coordinate Mg is rare, its structure is reported here. The Mg atom lies on a twofold axis and is surrounded by two O atoms and two Cl atoms in a distorted tetrahedral coordination geometry.",

author = "Kucera, {Benjamin E.} and Olmstead, {Marilyn M.} and Tanke, {Robin S.} and Kauzlarich, {Susan M.}",

year = "2003",

month = jun,

doi = "10.1107/S1600536803009723",

language = "English (US)",

volume = "59",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "6",

}

TY - JOUR

T1 - Dichlorobis(triphenylphosphine oxide)magnesium

AU - Kucera, Benjamin E.

AU - Olmstead, Marilyn M.

AU - Tanke, Robin S.

AU - Kauzlarich, Susan M.

PY - 2003/6

Y1 - 2003/6

N2 - The compound [MgCl2(C18H15OP)2] was inadvertantly crystallized during a reaction involving magnesium germanide. It is isostructural to the Mn, Co, Cu and Zn analogs. Since four-coordinate Mg is rare, its structure is reported here. The Mg atom lies on a twofold axis and is surrounded by two O atoms and two Cl atoms in a distorted tetrahedral coordination geometry.

AB - The compound [MgCl2(C18H15OP)2] was inadvertantly crystallized during a reaction involving magnesium germanide. It is isostructural to the Mn, Co, Cu and Zn analogs. Since four-coordinate Mg is rare, its structure is reported here. The Mg atom lies on a twofold axis and is surrounded by two O atoms and two Cl atoms in a distorted tetrahedral coordination geometry.

UR - http://www.scopus.com/inward/record.url?scp=18444382055&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=18444382055&partnerID=8YFLogxK

U2 - 10.1107/S1600536803009723

DO - 10.1107/S1600536803009723

M3 - Article

AN - SCOPUS:18444382055

VL - 59

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 6

ER -