Dichlorobis(triphenylphosphine oxide)magnesium

Benjamin E. Kucera; Marilyn M. Olmstead; Robin S. Tanke; Susan M. Kauzlarich

doi:10.1107/S1600536803009723

Dichlorobis(triphenylphosphine oxide)magnesium

Benjamin E. Kucera, Marilyn M. Olmstead, Robin S. Tanke, Susan M. Kauzlarich

Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The compound [MgCl₂(C₁₈H₁₅OP)₂] was inadvertantly crystallized during a reaction involving magnesium germanide. It is isostructural to the Mn, Co, Cu and Zn analogs. Since four-coordinate Mg is rare, its structure is reported here. The Mg atom lies on a twofold axis and is surrounded by two O atoms and two Cl atoms in a distorted tetrahedral coordination geometry.

Original language	English (US)
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	6
DOIs	https://doi.org/10.1107/S1600536803009723
State	Published - Jun 2003

ASJC Scopus subject areas

Condensed Matter Physics
Structural Biology

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title = "Dichlorobis(triphenylphosphine oxide)magnesium",

abstract = "The compound [MgCl2(C18H15OP)2] was inadvertantly crystallized during a reaction involving magnesium germanide. It is isostructural to the Mn, Co, Cu and Zn analogs. Since four-coordinate Mg is rare, its structure is reported here. The Mg atom lies on a twofold axis and is surrounded by two O atoms and two Cl atoms in a distorted tetrahedral coordination geometry.",

author = "Kucera, {Benjamin E.} and Olmstead, {Marilyn M.} and Tanke, {Robin S.} and Kauzlarich, {Susan M.}",

year = "2003",

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T1 - Dichlorobis(triphenylphosphine oxide)magnesium

AU - Kucera, Benjamin E.

AU - Olmstead, Marilyn M.

AU - Tanke, Robin S.

AU - Kauzlarich, Susan M.

PY - 2003/6

Y1 - 2003/6

N2 - The compound [MgCl2(C18H15OP)2] was inadvertantly crystallized during a reaction involving magnesium germanide. It is isostructural to the Mn, Co, Cu and Zn analogs. Since four-coordinate Mg is rare, its structure is reported here. The Mg atom lies on a twofold axis and is surrounded by two O atoms and two Cl atoms in a distorted tetrahedral coordination geometry.

AB - The compound [MgCl2(C18H15OP)2] was inadvertantly crystallized during a reaction involving magnesium germanide. It is isostructural to the Mn, Co, Cu and Zn analogs. Since four-coordinate Mg is rare, its structure is reported here. The Mg atom lies on a twofold axis and is surrounded by two O atoms and two Cl atoms in a distorted tetrahedral coordination geometry.

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Dichlorobis(triphenylphosphine oxide)magnesium

Abstract

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