Dicarbon monofluoride: A solid host for containment of volatiles

Maryam Afkarian, John R. Sedy, Jianfei Yang, Nils G. Jacobson, Nezih Cereb, Soo Y. Yang, Theresa L. Murphy, Kenneth M. Murphy

Research output: Contribution to journalArticle

15 Scopus citations

Abstract

Graphite fluoride with a C : F atomic ratio close to 2 was prepared by reacting graphite with liquid ClF3 (20°C), solutions of ClF 3 in anhydrous hydrogen fluoride and Freon-113 (20°C), ClF 3 gas (50-100°C), and ClF3 + HF gas mixtures (20-100°C). The results on the thermal stability of C2F intercalated with various organic compounds, in conjunction with earlier reported data, demonstrate that, below the exothermic decomposition temperatures of the intercalates, C2F is a suitable host material for the containment of volatile compounds, which is superior to the other known inclusion compounds in thermal stability and versatility.

Original languageEnglish (US)
Pages (from-to)278-282
Number of pages5
JournalInorganic Materials
Volume38
Issue number3
DOIs
StatePublished - Jan 1 2002
Externally publishedYes

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Inorganic Chemistry
  • Metals and Alloys
  • Materials Chemistry

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    Afkarian, M., Sedy, J. R., Yang, J., Jacobson, N. G., Cereb, N., Yang, S. Y., Murphy, T. L., & Murphy, K. M. (2002). Dicarbon monofluoride: A solid host for containment of volatiles. Inorganic Materials, 38(3), 278-282. https://doi.org/10.1023/A:1014783119281