Cyclohexane-linked indenyl rings in 5,8-bis(trimethylsilyl)-6,7,12b,12c-tetrahydroindeno[2,1-c]fluorene

Marilyn M. Olmstead; Shawn R. Hitchcock; Michael H. Nantz

Cyclohexane-linked indenyl rings in 5,8-bis(trimethylsilyl)-6,7,12b,12c-tetrahydroindeno[2,1-c]fluorene

Marilyn M. Olmstead, Shawn R. Hitchcock, Michael H. Nantz

Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A novel ring structure of formula C₂₆H₃₂Si₂ has been formed by oxidation of 1,2-bis(1-trimethylsilyl-2-indenyl)ethane during attempted TiCl₃(tHf)₃ complexation. Two indenyl groups are linked by a cyclohexane ring having a chair conformation and the resulting dihedral angle between the planes of the indenyl groups is 10.6(1)°.

Original language	English (US)
Pages (from-to)	1523-1525
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	6
State	Published - Jun 15 1996

ASJC Scopus subject areas

Condensed Matter Physics
Structural Biology

Cite this

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title = "Cyclohexane-linked indenyl rings in 5,8-bis(trimethylsilyl)-6,7,12b,12c-tetrahydroindeno[2,1-c]fluorene",

abstract = "A novel ring structure of formula C26H32Si2 has been formed by oxidation of 1,2-bis(1-trimethylsilyl-2-indenyl)ethane during attempted TiCl3(tHf)3 complexation. Two indenyl groups are linked by a cyclohexane ring having a chair conformation and the resulting dihedral angle between the planes of the indenyl groups is 10.6(1)°.",

author = "Olmstead, {Marilyn M.} and Hitchcock, {Shawn R.} and Nantz, {Michael H.}",

year = "1996",

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journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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T1 - Cyclohexane-linked indenyl rings in 5,8-bis(trimethylsilyl)-6,7,12b,12c-tetrahydroindeno[2,1-c]fluorene

AU - Olmstead, Marilyn M.

AU - Hitchcock, Shawn R.

AU - Nantz, Michael H.

PY - 1996/6/15

Y1 - 1996/6/15

N2 - A novel ring structure of formula C26H32Si2 has been formed by oxidation of 1,2-bis(1-trimethylsilyl-2-indenyl)ethane during attempted TiCl3(tHf)3 complexation. Two indenyl groups are linked by a cyclohexane ring having a chair conformation and the resulting dihedral angle between the planes of the indenyl groups is 10.6(1)°.

AB - A novel ring structure of formula C26H32Si2 has been formed by oxidation of 1,2-bis(1-trimethylsilyl-2-indenyl)ethane during attempted TiCl3(tHf)3 complexation. Two indenyl groups are linked by a cyclohexane ring having a chair conformation and the resulting dihedral angle between the planes of the indenyl groups is 10.6(1)°.

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M3 - Article

AN - SCOPUS:0030171539

VL - 52

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EP - 1525

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 6

ER -

Cyclohexane-linked indenyl rings in 5,8-bis(trimethylsilyl)-6,7,12b,12c-tetrahydroindeno[2,1-c]fluorene

Abstract

ASJC Scopus subject areas

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