Abstract
Divinylbenzene (DVB) and diethylene glycol bis(4-vinylbenzyl) ether (DEG) were used as crosslinkers in the preparation of four resins of mixed micro- and macroporous character and differing polarity to examine the effects of crosslinker structure and macroporosity. The Suzuki coupling process was used as the probe reaction for this purpose. Results with 2% DVB, 2% DEG, 5% DEG and 15% DEG indicate that the DEG-crosslinked resins are somewhat better suited for this process, although the degree of crosslinking appears to have only minimal effect of degree of conversion to product.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 131-137 |
| Number of pages | 7 |
| Journal | Reactive and Functional Polymers |
| Volume | 55 |
| Issue number | 2 |
| DOIs | |
| State | Published - Apr 2003 |
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Keywords
- Coupling reaction
- Crosslinker
- Polymer
- Solid-phase synthesis
- Suzuki reaction
ASJC Scopus subject areas
- Organic Chemistry
- Polymers and Plastics
Cite this
Customized solid supports for small-molecule synthesis : Effects of crosslinking structure and degree. / Price, Michael D.; Radosevich, Jennifer L.; Kurth, Mark J.; Schore, Neil E.
In: Reactive and Functional Polymers, Vol. 55, No. 2, 04.2003, p. 131-137.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Customized solid supports for small-molecule synthesis
T2 - Effects of crosslinking structure and degree
AU - Price, Michael D.
AU - Radosevich, Jennifer L.
AU - Kurth, Mark J.
AU - Schore, Neil E.
PY - 2003/4
Y1 - 2003/4
N2 - Divinylbenzene (DVB) and diethylene glycol bis(4-vinylbenzyl) ether (DEG) were used as crosslinkers in the preparation of four resins of mixed micro- and macroporous character and differing polarity to examine the effects of crosslinker structure and macroporosity. The Suzuki coupling process was used as the probe reaction for this purpose. Results with 2% DVB, 2% DEG, 5% DEG and 15% DEG indicate that the DEG-crosslinked resins are somewhat better suited for this process, although the degree of crosslinking appears to have only minimal effect of degree of conversion to product.
AB - Divinylbenzene (DVB) and diethylene glycol bis(4-vinylbenzyl) ether (DEG) were used as crosslinkers in the preparation of four resins of mixed micro- and macroporous character and differing polarity to examine the effects of crosslinker structure and macroporosity. The Suzuki coupling process was used as the probe reaction for this purpose. Results with 2% DVB, 2% DEG, 5% DEG and 15% DEG indicate that the DEG-crosslinked resins are somewhat better suited for this process, although the degree of crosslinking appears to have only minimal effect of degree of conversion to product.
KW - Coupling reaction
KW - Crosslinker
KW - Polymer
KW - Solid-phase synthesis
KW - Suzuki reaction
UR - http://www.scopus.com/inward/record.url?scp=0037393611&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037393611&partnerID=8YFLogxK
U2 - 10.1016/S1381-5148(02)00222-5
DO - 10.1016/S1381-5148(02)00222-5
M3 - Article
AN - SCOPUS:0037393611
VL - 55
SP - 131
EP - 137
JO - Reactive and Functional Polymers
JF - Reactive and Functional Polymers
SN - 1381-5148
IS - 2
ER -