Construction of the oxetane ring from 5α-acyloxy-Δ 4(20)-taxoids

Ruiwu Liu, Ji Yu Guo, Xiao Tian Liang

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

An oxetane ring can be constructed from 5α-acyloxy-Δ 4(20)-taxoids with osmylation as the first step in the usual manner. The innovation reported here is the use of an intramolecularly available acyl group for the protection of 20-OH by an unexpected 5-to 20-migration under slightly basic conditions.

Original languageEnglish (US)
Pages (from-to)99-100
Number of pages2
JournalChinese Chemical Letters
Volume8
Issue number2
StatePublished - 1997
Externally publishedYes

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Taxoids
Innovation
oxetane

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Liu, R., Guo, J. Y., & Liang, X. T. (1997). Construction of the oxetane ring from 5α-acyloxy-Δ 4(20)-taxoids. Chinese Chemical Letters, 8(2), 99-100.

Construction of the oxetane ring from 5α-acyloxy-Δ 4(20)-taxoids. / Liu, Ruiwu; Guo, Ji Yu; Liang, Xiao Tian.

In: Chinese Chemical Letters, Vol. 8, No. 2, 1997, p. 99-100.

Research output: Contribution to journalArticle

Liu, R, Guo, JY & Liang, XT 1997, 'Construction of the oxetane ring from 5α-acyloxy-Δ 4(20)-taxoids', Chinese Chemical Letters, vol. 8, no. 2, pp. 99-100.
Liu, Ruiwu ; Guo, Ji Yu ; Liang, Xiao Tian. / Construction of the oxetane ring from 5α-acyloxy-Δ 4(20)-taxoids. In: Chinese Chemical Letters. 1997 ; Vol. 8, No. 2. pp. 99-100.
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