Abstract
A fundamental study of the conformations of [7.7]-, [8.8]-, [9.9]-, [11.11]- and octamethyl[8.8]-paracyclophanes in the solid state shows that the [odd.odd] members of the series possess parallel, symmetrically disposed benzene rings. A new genre of inclusion phenomenon based on donor-halogen EDA interactions is also defined and the potential of cyclophanes to act as hosts both in this capacity and to benzenes is discussed.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1141-1151 |
| Number of pages | 11 |
| Journal | Journal of the Chemical Society - Perkin Transactions 1 |
| Issue number | 11 |
| State | Published - Jun 7 1996 |
| Externally published | Yes |
ASJC Scopus subject areas
- Organic Chemistry
- Chemistry(all)
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Mascal, M., Kerdelhué, J. L., Batsanov, A. S., & Begley, M. J. (1996). Conformational study of the higher [n.n]paracyclophanes: Evaluation as potential hosts for molecular halogens and benzenes. Journal of the Chemical Society - Perkin Transactions 1, (11), 1141-1151.