Characterization of buried metal-molecule-metal junctions using Fourier transform infrared microspectroscopy

Christopher B. Babayco, Donald P. Land, Atul N. Parikh, Richard A. Kiehl

Research output: Contribution to journalArticle

Abstract

We have devised an infrared spectromicroscopy based experimental configuration to enable structural characterization of buried molecular junctions. Our design utilizes a small mercury drop at the focal point of an infrared microscope to act as a mirror in studying metal-molecule-metal (MmM) junctions. An organic molecular monolayer is formed either directly on the mercury drop or on a thin, infrared (IR) semi-transparent layer of Au deposited onto an IR transparent, undoped silicon substrate. Following the formation of the monolayer, films on either metal can be examined independently using specular reflection spectroscopy. Furthermore, by bringing together the two monolayers, a buried molecular bilayer within the MmM junction can be characterized. Independent examination of each half of the junction prior to junction formation also allows probing any structural and/or conformational changes that occur as a result of forming the bilayer. Because our approach allows assembling and disassembling microscopic junctions by forming and withdrawing Hg drops onto the monolayer covered metal, spatial mapping of junctions can be performed simply by translating the location of the derivatized silicon wafer. Finally, the applicability of this technique for the longer-term studies of changes in molecular structure in the presence of electrical bias is discussed.

Original languageEnglish (US)
Article numberA81
JournalReview of Scientific Instruments
Volume85
Issue number9
DOIs
StatePublished - Sep 1 2014

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Fourier transforms
Infrared radiation
Molecules
Monolayers
Metals
metals
molecules
translating
specular reflection
Silicon wafers
Molecular structure
silicon
assembling
Mirrors
Microscopes
Spectroscopy
molecular structure
examination
microscopes
Silicon

ASJC Scopus subject areas

  • Instrumentation

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Characterization of buried metal-molecule-metal junctions using Fourier transform infrared microspectroscopy. / Babayco, Christopher B.; Land, Donald P.; Parikh, Atul N.; Kiehl, Richard A.

In: Review of Scientific Instruments, Vol. 85, No. 9, A81, 01.09.2014.

Research output: Contribution to journalArticle

Babayco, Christopher B. ; Land, Donald P. ; Parikh, Atul N. ; Kiehl, Richard A. / Characterization of buried metal-molecule-metal junctions using Fourier transform infrared microspectroscopy. In: Review of Scientific Instruments. 2014 ; Vol. 85, No. 9.
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