Characterization and potential environmental risks of leachate from shredded rubber mulches

Masakazu Kanematsu, Ai Hayashi, Michael S. Denison, Thomas M. Young

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

In order to determine whether shredded rubber mulches (RM) pose water quality risks when used in stormwater best management practices (BMPs) such as bioretention basins, batch leaching tests were conducted to identify and quantify constituents in leachates from RM such as metal ions, nutrients, total organic carbon (TOC), and aryl hydrocarbon receptor (AhR) activity (determined by the chemically activated luciferase gene expression (CALUX) bioassay) at varied temperature and initial pH values. The results indicate that aqueous extracts of RM contain high concentrations of zinc (Zn) compared with wood mulches (WM), and its concentration increased at lower pH and higher temperature. Although methanol extracts of RM displayed high AhR activity, none of the aqueous extracts of RM had significant activity. Hence, while unknown constituents that have significant AhR activity are present in RM, they appear to be not measurably extracted by water under environmental conditions relevant for stormwater (5 < pH < 9, 10 < T < 40 °C). Our results suggest that organic constituents in water extracts of RM which have AhR activity may not be of significant concern while leaching of Zn from RM appears to be a potentially larger water quality issue for RM.

Original languageEnglish (US)
Pages (from-to)952-958
Number of pages7
JournalChemosphere
Volume76
Issue number7
DOIs
StatePublished - Aug 2009

Fingerprint

Rubber
rubber
environmental risk
leachate
Aryl Hydrocarbon Receptors
Hydrocarbons
hydrocarbon
Water Quality
stormwater
Leaching
Water quality
Zinc
zinc
leaching
water quality
Temperature
Water
Bioassay
best management practice
Organic carbon

Keywords

  • Ah receptor activity
  • Shredded rubber mulch
  • Wood mulches
  • Zinc

ASJC Scopus subject areas

  • Environmental Chemistry
  • Chemistry(all)

Cite this

Characterization and potential environmental risks of leachate from shredded rubber mulches. / Kanematsu, Masakazu; Hayashi, Ai; Denison, Michael S.; Young, Thomas M.

In: Chemosphere, Vol. 76, No. 7, 08.2009, p. 952-958.

Research output: Contribution to journalArticle

Kanematsu, Masakazu ; Hayashi, Ai ; Denison, Michael S. ; Young, Thomas M. / Characterization and potential environmental risks of leachate from shredded rubber mulches. In: Chemosphere. 2009 ; Vol. 76, No. 7. pp. 952-958.
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