Carbonic anhydrase mimics for enhanced CO2 absorption in an amine-based capture solvent

Rachael A. Kelsey, David A. Miller, Sean R. Parkin, Kun Liu, Joe E. Remias, Yue Yang, Felice C Lightstone, Kunlei Liu, Cameron A. Lippert, Susan A. Odom

Research output: Contribution to journalArticle

16 Scopus citations

Abstract

Two new small-molecule enzyme mimics of carbonic anhydrase were prepared and characterized. These complexes contain the salen-like ligand bis(hydroxyphenyl)phenanthroline. This ligand is similar to the salen-type ligands previously incorporated into carbonic anhydrase mimics but contains no hydrolyzable imine groups and therefore serves as a promising ligand scaffold for the synthesis of a more robust CO2 hydration catalyst. These homogeneous catalysts were investigated for CO2 hydration in concentrated primary amine solutions through which a dilute CO2 (14%) fluid stream was flowed and showed exceptional activity for increased CO2 absorption rates.

Original languageEnglish (US)
Pages (from-to)324-333
Number of pages10
JournalDalton Transactions
Volume45
Issue number1
DOIs
Publication statusPublished - Nov 26 2015
Externally publishedYes

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ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Kelsey, R. A., Miller, D. A., Parkin, S. R., Liu, K., Remias, J. E., Yang, Y., ... Odom, S. A. (2015). Carbonic anhydrase mimics for enhanced CO2 absorption in an amine-based capture solvent. Dalton Transactions, 45(1), 324-333. https://doi.org/10.1039/c5dt02943k