Bilateral, difunctional nanosphere aggregates and their assembly mediated by polymer chains

S. M. Barber, P. J. Costanzo, N. W. Moore, T. E. Patten, K. S. Lancaster, Carlito B Lebrilla, T. L. Kuhl

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

We have developed an efficient method for producing difunctional, bilateral nanospheres. A monolayer of nanoparticles was prepared followed by deposition of a thin layer of metal. By varying the base particle and metal deposited, bilateral nanoparticles were formed. The different regions of the nanoparticles were selectively functionalized with polymer linkers containing specific terminal groups, thereby creating bilateral, difunctional nanoparticles. Subsequent covalent cross-linking of different nanoparticles enabled the formation of stable architectures with programmed hierarchy and controlled chemical composition.

Original languageEnglish (US)
Pages (from-to)4538-4542
Number of pages5
JournalJournal of Physical Chemistry A
Volume110
Issue number13
DOIs
StatePublished - Apr 6 2006

Fingerprint

Nanospheres
Polymers
assembly
Nanoparticles
nanoparticles
polymers
Metals
metals
hierarchies
Monolayers
chemical composition
Chemical analysis

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Barber, S. M., Costanzo, P. J., Moore, N. W., Patten, T. E., Lancaster, K. S., Lebrilla, C. B., & Kuhl, T. L. (2006). Bilateral, difunctional nanosphere aggregates and their assembly mediated by polymer chains. Journal of Physical Chemistry A, 110(13), 4538-4542. https://doi.org/10.1021/jp0560617

Bilateral, difunctional nanosphere aggregates and their assembly mediated by polymer chains. / Barber, S. M.; Costanzo, P. J.; Moore, N. W.; Patten, T. E.; Lancaster, K. S.; Lebrilla, Carlito B; Kuhl, T. L.

In: Journal of Physical Chemistry A, Vol. 110, No. 13, 06.04.2006, p. 4538-4542.

Research output: Contribution to journalArticle

Barber, SM, Costanzo, PJ, Moore, NW, Patten, TE, Lancaster, KS, Lebrilla, CB & Kuhl, TL 2006, 'Bilateral, difunctional nanosphere aggregates and their assembly mediated by polymer chains', Journal of Physical Chemistry A, vol. 110, no. 13, pp. 4538-4542. https://doi.org/10.1021/jp0560617
Barber SM, Costanzo PJ, Moore NW, Patten TE, Lancaster KS, Lebrilla CB et al. Bilateral, difunctional nanosphere aggregates and their assembly mediated by polymer chains. Journal of Physical Chemistry A. 2006 Apr 6;110(13):4538-4542. https://doi.org/10.1021/jp0560617
Barber, S. M. ; Costanzo, P. J. ; Moore, N. W. ; Patten, T. E. ; Lancaster, K. S. ; Lebrilla, Carlito B ; Kuhl, T. L. / Bilateral, difunctional nanosphere aggregates and their assembly mediated by polymer chains. In: Journal of Physical Chemistry A. 2006 ; Vol. 110, No. 13. pp. 4538-4542.
@article{5cf1e15e5e954bb39c17fae9c6ed32a9,
title = "Bilateral, difunctional nanosphere aggregates and their assembly mediated by polymer chains",
abstract = "We have developed an efficient method for producing difunctional, bilateral nanospheres. A monolayer of nanoparticles was prepared followed by deposition of a thin layer of metal. By varying the base particle and metal deposited, bilateral nanoparticles were formed. The different regions of the nanoparticles were selectively functionalized with polymer linkers containing specific terminal groups, thereby creating bilateral, difunctional nanoparticles. Subsequent covalent cross-linking of different nanoparticles enabled the formation of stable architectures with programmed hierarchy and controlled chemical composition.",
author = "Barber, {S. M.} and Costanzo, {P. J.} and Moore, {N. W.} and Patten, {T. E.} and Lancaster, {K. S.} and Lebrilla, {Carlito B} and Kuhl, {T. L.}",
year = "2006",
month = "4",
day = "6",
doi = "10.1021/jp0560617",
language = "English (US)",
volume = "110",
pages = "4538--4542",
journal = "Journal of Physical Chemistry A",
issn = "1089-5639",
publisher = "American Chemical Society",
number = "13",

}

TY - JOUR

T1 - Bilateral, difunctional nanosphere aggregates and their assembly mediated by polymer chains

AU - Barber, S. M.

AU - Costanzo, P. J.

AU - Moore, N. W.

AU - Patten, T. E.

AU - Lancaster, K. S.

AU - Lebrilla, Carlito B

AU - Kuhl, T. L.

PY - 2006/4/6

Y1 - 2006/4/6

N2 - We have developed an efficient method for producing difunctional, bilateral nanospheres. A monolayer of nanoparticles was prepared followed by deposition of a thin layer of metal. By varying the base particle and metal deposited, bilateral nanoparticles were formed. The different regions of the nanoparticles were selectively functionalized with polymer linkers containing specific terminal groups, thereby creating bilateral, difunctional nanoparticles. Subsequent covalent cross-linking of different nanoparticles enabled the formation of stable architectures with programmed hierarchy and controlled chemical composition.

AB - We have developed an efficient method for producing difunctional, bilateral nanospheres. A monolayer of nanoparticles was prepared followed by deposition of a thin layer of metal. By varying the base particle and metal deposited, bilateral nanoparticles were formed. The different regions of the nanoparticles were selectively functionalized with polymer linkers containing specific terminal groups, thereby creating bilateral, difunctional nanoparticles. Subsequent covalent cross-linking of different nanoparticles enabled the formation of stable architectures with programmed hierarchy and controlled chemical composition.

UR - http://www.scopus.com/inward/record.url?scp=33646376454&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33646376454&partnerID=8YFLogxK

U2 - 10.1021/jp0560617

DO - 10.1021/jp0560617

M3 - Article

C2 - 16571061

AN - SCOPUS:33646376454

VL - 110

SP - 4538

EP - 4542

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

SN - 1089-5639

IS - 13

ER -