Abstract
Azatriquinane, a tricyclic amine with rigid, hemispherical topology, is synthesized in six steps from pyrrole. This first example of a [2.2.2]cyclazine can be oxidatively dimerized to a novel, highly strained heptacycle or oxidized with chlorine to give an azatriquinacene, a theoretical precursor to diazadodecahedrane via Woodward dimerization.
Original language | English (US) |
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Pages (from-to) | 6016-6020 |
Number of pages | 5 |
Journal | Journal of Organic Chemistry |
Volume | 63 |
Issue number | 17 |
State | Published - Aug 21 1998 |
Externally published | Yes |
ASJC Scopus subject areas
- Organic Chemistry