Asymmetric aza-Claisen rearrangement: Synthesis of (+)-dihydropallescensin-2 [(+)-penlanpallescensin].

Mark J. Kurth; Christopher J. Soares

doi:10.1016/S0040-4039(00)95903-3

Asymmetric aza-Claisen rearrangement: Synthesis of (+)-dihydropallescensin-2 [(+)-penlanpallescensin].

Mark J. Kurth, Christopher J. Soares

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Synthetic confirmation of the C(1′)-(S)-configuration of (+)-dihydropallescensin-2 (1) is reported, the key reaction being a chiron-mediated asymmetric aza-Claisen rearrangement (6→7).

Original language	English (US)
Pages (from-to)	1031-1034
Number of pages	4
Journal	Tetrahedron Letters
Volume	28
Issue number	10
DOIs	https://doi.org/10.1016/S0040-4039(00)95903-3
State	Published - 1987
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Drug Discovery

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title = "Asymmetric aza-Claisen rearrangement: Synthesis of (+)-dihydropallescensin-2 [(+)-penlanpallescensin].",

abstract = "Synthetic confirmation of the C(1′)-(S)-configuration of (+)-dihydropallescensin-2 (1) is reported, the key reaction being a chiron-mediated asymmetric aza-Claisen rearrangement (6→7).",

author = "Kurth, {Mark J.} and Soares, {Christopher J.}",

year = "1987",

doi = "10.1016/S0040-4039(00)95903-3",

language = "English (US)",

volume = "28",

pages = "1031--1034",

journal = "Tetrahedron Letters",

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TY - JOUR

T1 - Asymmetric aza-Claisen rearrangement

T2 - Synthesis of (+)-dihydropallescensin-2 [(+)-penlanpallescensin].

AU - Kurth, Mark J.

AU - Soares, Christopher J.

PY - 1987

Y1 - 1987

N2 - Synthetic confirmation of the C(1′)-(S)-configuration of (+)-dihydropallescensin-2 (1) is reported, the key reaction being a chiron-mediated asymmetric aza-Claisen rearrangement (6→7).

AB - Synthetic confirmation of the C(1′)-(S)-configuration of (+)-dihydropallescensin-2 (1) is reported, the key reaction being a chiron-mediated asymmetric aza-Claisen rearrangement (6→7).

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UR - http://www.scopus.com/inward/citedby.url?scp=0000161770&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)95903-3

DO - 10.1016/S0040-4039(00)95903-3

M3 - Article

AN - SCOPUS:0000161770

VL - 28

SP - 1031

EP - 1034

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 10

ER -

Asymmetric aza-Claisen rearrangement: Synthesis of (+)-dihydropallescensin-2 [(+)-penlanpallescensin].

Abstract

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