Abstract
Synthetic confirmation of the C(1′)-(S)-configuration of (+)-dihydropallescensin-2 (1) is reported, the key reaction being a chiron-mediated asymmetric aza-Claisen rearrangement (6→7).
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1031-1034 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 28 |
| Issue number | 10 |
| DOIs | |
| State | Published - 1987 |
| Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Drug Discovery
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Kurth, M. J., & Soares, C. J. (1987). Asymmetric aza-Claisen rearrangement: Synthesis of (+)-dihydropallescensin-2 [(+)-penlanpallescensin]. Tetrahedron Letters, 28(10), 1031-1034. https://doi.org/10.1016/S0040-4039(00)95903-3