Asymmetric aza-Claisen rearrangement: Synthesis of (+)-dihydropallescensin-2 [(+)-penlanpallescensin].

Mark J. Kurth, Christopher J. Soares

Research output: Contribution to journalArticle

36 Scopus citations

Abstract

Synthetic confirmation of the C(1′)-(S)-configuration of (+)-dihydropallescensin-2 (1) is reported, the key reaction being a chiron-mediated asymmetric aza-Claisen rearrangement (6→7).

Original languageEnglish (US)
Pages (from-to)1031-1034
Number of pages4
JournalTetrahedron Letters
Volume28
Issue number10
DOIs
StatePublished - 1987
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

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