Asymmetric aza-Claisen rearrangement: Synthesis of (+)-dihydropallescensin-2 [(+)-penlanpallescensin].

Mark J. Kurth, Christopher J. Soares

Research output: Contribution to journalArticlepeer-review

37 Scopus citations


Synthetic confirmation of the C(1′)-(S)-configuration of (+)-dihydropallescensin-2 (1) is reported, the key reaction being a chiron-mediated asymmetric aza-Claisen rearrangement (6→7).

Original languageEnglish (US)
Pages (from-to)1031-1034
Number of pages4
JournalTetrahedron Letters
Issue number10
StatePublished - 1987
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery


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