A thioxanone-based chiral template: Asymmetric induction in the [2,3]-sigmatropic rearrangement of sulfur ylids. Enantioselective preparation of Cβ-chiral pent-4-enoic acids

Mark J. Kurth, S. Hasan Tahir, Marilyn M. Olmstead

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

A thioxanone-based [2,3]-sigmatropic rearrangement strategy which delivers Cβ-chiral pent-4-enoic acids with excellent Cβ-induction is reported.

Original languageEnglish (US)
Pages (from-to)2286-2288
Number of pages3
JournalJournal of Organic Chemistry
Volume55
Issue number8
StatePublished - 1990

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Sulfur
Acids

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

A thioxanone-based chiral template : Asymmetric induction in the [2,3]-sigmatropic rearrangement of sulfur ylids. Enantioselective preparation of Cβ-chiral pent-4-enoic acids. / Kurth, Mark J.; Tahir, S. Hasan; Olmstead, Marilyn M.

In: Journal of Organic Chemistry, Vol. 55, No. 8, 1990, p. 2286-2288.

Research output: Contribution to journalArticle

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abstract = "A thioxanone-based [2,3]-sigmatropic rearrangement strategy which delivers Cβ-chiral pent-4-enoic acids with excellent Cβ-induction is reported.",
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