Abstract
A theoretical analysis of MCD and absorption is made for transitions involving J = 0 and J = 1 states using a general field model. Magnetic dipole, electric dipole, and electric quadrupole contributions are considered. The ratio of absorption intensity to first moment of MCD is shown to depend on the g-factor and the fractional contribution of the various types of transition moments. The theory is applied to the 7F0 → 5D0 and anhydrous ethanol and leads to the conclusion that the europium ion has low symmetry in both solvents. The theory is also applied to the 7F1 → 5D0 transition of EuCl3 in water.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 171-180 |
| Number of pages | 10 |
| Journal | Chemical Physics |
| Volume | 36 |
| Issue number | 2 |
| DOIs | |
| State | Published - Jan 15 1979 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
Cite this
A theoretical analysis of magnetic circular dichroism ofthe 7F0 → 5D1 and 7F1 → 5D0 transitions in solutions of EuC. / Sage, Martin L.; Buonocore, Michael H.; Pink, Harry S.
In: Chemical Physics, Vol. 36, No. 2, 15.01.1979, p. 171-180.Research output: Contribution to journal › Article
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TY - JOUR
T1 - A theoretical analysis of magnetic circular dichroism ofthe 7F0 → 5D1 and 7F1 → 5D0 transitions in solutions of EuC
AU - Sage, Martin L.
AU - Buonocore, Michael H.
AU - Pink, Harry S.
PY - 1979/1/15
Y1 - 1979/1/15
N2 - A theoretical analysis of MCD and absorption is made for transitions involving J = 0 and J = 1 states using a general field model. Magnetic dipole, electric dipole, and electric quadrupole contributions are considered. The ratio of absorption intensity to first moment of MCD is shown to depend on the g-factor and the fractional contribution of the various types of transition moments. The theory is applied to the 7F0 → 5D0 and anhydrous ethanol and leads to the conclusion that the europium ion has low symmetry in both solvents. The theory is also applied to the 7F1 → 5D0 transition of EuCl3 in water.
AB - A theoretical analysis of MCD and absorption is made for transitions involving J = 0 and J = 1 states using a general field model. Magnetic dipole, electric dipole, and electric quadrupole contributions are considered. The ratio of absorption intensity to first moment of MCD is shown to depend on the g-factor and the fractional contribution of the various types of transition moments. The theory is applied to the 7F0 → 5D0 and anhydrous ethanol and leads to the conclusion that the europium ion has low symmetry in both solvents. The theory is also applied to the 7F1 → 5D0 transition of EuCl3 in water.
UR - http://www.scopus.com/inward/record.url?scp=4344657117&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=4344657117&partnerID=8YFLogxK
U2 - 10.1016/0301-0104(79)85003-X
DO - 10.1016/0301-0104(79)85003-X
M3 - Article
AN - SCOPUS:4344657117
VL - 36
SP - 171
EP - 180
JO - Chemical Physics
JF - Chemical Physics
SN - 0301-0104
IS - 2
ER -