A convenient terminal allene synthesis from propargylic acetates

M. H. Nantz; D. M. Bender; S. Janaki

A convenient terminal allene synthesis from propargylic acetates

M. H. Nantz, D. M. Bender, S. Janaki

Chemistry

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The use of lithium butyl(phenylthio)cuprate as a reactant with propargylic acetates for the synthesis of terminal allenes is reported. Treatment of propargylic acetates with lithium butyl(phenylthio)cuprate in diethyl ether at -78°C yields the title compounds on workup with aqueous ammonium chloride.

Original language	English (US)
Pages (from-to)	577-578
Number of pages	2
Journal	Synthesis
Issue number	6
State	Published - 1993

ASJC Scopus subject areas

Organic Chemistry

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title = "A convenient terminal allene synthesis from propargylic acetates",

abstract = "The use of lithium butyl(phenylthio)cuprate as a reactant with propargylic acetates for the synthesis of terminal allenes is reported. Treatment of propargylic acetates with lithium butyl(phenylthio)cuprate in diethyl ether at -78°C yields the title compounds on workup with aqueous ammonium chloride.",

author = "Nantz, {M. H.} and Bender, {D. M.} and S. Janaki",

year = "1993",

language = "English (US)",

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journal = "Synthesis (Germany)",

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T1 - A convenient terminal allene synthesis from propargylic acetates

AU - Nantz, M. H.

AU - Bender, D. M.

AU - Janaki, S.

PY - 1993

Y1 - 1993

N2 - The use of lithium butyl(phenylthio)cuprate as a reactant with propargylic acetates for the synthesis of terminal allenes is reported. Treatment of propargylic acetates with lithium butyl(phenylthio)cuprate in diethyl ether at -78°C yields the title compounds on workup with aqueous ammonium chloride.

AB - The use of lithium butyl(phenylthio)cuprate as a reactant with propargylic acetates for the synthesis of terminal allenes is reported. Treatment of propargylic acetates with lithium butyl(phenylthio)cuprate in diethyl ether at -78°C yields the title compounds on workup with aqueous ammonium chloride.

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JO - Synthesis (Germany)

JF - Synthesis (Germany)

SN - 0039-7881

IS - 6

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