Abstract
Diastereoselective S-allylation of thioxanone 6 and subsequent ylid formation/[2,3]-sigmatropic rearrangement delivers excellent Cα-induction. Non-stereospecific Cβ-induction results from scrambling of olefin geometry in the S-allylation step.
Original language | English (US) |
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Pages (from-to) | 335-338 |
Number of pages | 4 |
Journal | Tetrahedron Letters |
Volume | 32 |
Issue number | 3 |
DOIs | |
State | Published - Jan 14 1991 |
Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Drug Discovery